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dc.contributor.authorPustovarenko, Alexey
dc.contributor.authorGoesten, Maarten G.
dc.contributor.authorSachdeva, Sumit
dc.contributor.authorShan, Meixia
dc.contributor.authorAmghouz, Zakariae
dc.contributor.authorBelmabkhout, Youssef
dc.contributor.authorDikhtiarenko, Alla
dc.contributor.authorRodenas, Tania
dc.contributor.authorKeskin, Damla
dc.contributor.authorVoets, Ilja K.
dc.contributor.authorWeckhuysen, Bert M.
dc.contributor.authorEddaoudi, Mohamed
dc.contributor.authorde Smet, Louis C. P. M.
dc.contributor.authorSudhölter, Ernst J. R.
dc.contributor.authorKapteijn, Freek
dc.contributor.authorSeoane, Beatriz
dc.contributor.authorGascon, Jorge
dc.date.accessioned2018-05-20T13:55:03Z
dc.date.available2018-05-20T13:55:03Z
dc.date.issued2018-05-18
dc.identifier.citationPustovarenko A, Goesten MG, Sachdeva S, Shan M, Amghouz Z, et al. (2018) Nanosheets of Nonlayered Aluminum Metal-Organic Frameworks through a Surfactant-Assisted Method. Advanced Materials: 1707234. Available: http://dx.doi.org/10.1002/adma.201707234.
dc.identifier.issn0935-9648
dc.identifier.pmid29774609
dc.identifier.doi10.1002/adma.201707234
dc.identifier.urihttp://hdl.handle.net/10754/627921
dc.description.abstractDuring the last decade, the synthesis and application of metal-organic framework (MOF) nanosheets has received growing interest, showing unique performances for different technological applications. Despite the potential of this type of nanolamellar materials, the synthetic routes developed so far are restricted to MOFs possessing layered structures, limiting further development in this field. Here, a bottom-up surfactant-assisted synthetic approach is presented for the fabrication of nanosheets of various nonlayered MOFs, broadening the scope of MOF nanosheets application. Surfactant-assisted preorganization of the metallic precursor prior to MOF synthesis enables the manufacture of nonlayered Al-containing MOF lamellae. These MOF nanosheets are shown to exhibit a superior performance over other crystal morphologies for both chemical sensing and gas separation. As revealed by electron microscopy and diffraction, this superior performance arises from the shorter diffusion pathway in the MOF nanosheets, whose 1D channels are oriented along the shortest particle dimension.
dc.description.sponsorshipB.S. gratefully acknowledges the Netherlands National Science Foundation (NWO) for her personal VENI grant. J.G. gratefully acknowledges the ERC Grant Agreement no. 335746, CrystEng-MOF-MMM. The authors also thank Mr. Duco Bosma and Mr. Bart Boshuizen from TU Delft for technical and LABVIEW support and Dr. Dimitri Soccol and Prof. Dirk J. Gravesteijn for providing us with the transducer platforms. I.K.V. acknowledges the Netherlands Organisation for Scientific Research (NWO ECHO-STIP Grant 717.013.005, NWOVIDI Grant 723.014.006) and the Dutch Ministry of Education, Culture and Science (Gravity Program 024.001.035) for financial support.
dc.publisherWiley
dc.relation.urlhttps://onlinelibrary.wiley.com/doi/abs/10.1002/adma.201707234
dc.rightsArchived with thanks to Advanced Materials
dc.subjectGas separation
dc.subjectmolecular recognition
dc.subjectChemical Sensing
dc.subjectCrystal Design
dc.subjectMetal-organic Framework Nanolamellae
dc.titleNanosheets of Nonlayered Aluminum Metal-Organic Frameworks through a Surfactant-Assisted Method
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Division
dc.contributor.departmentChemical Science Program
dc.contributor.departmentChemical and Biological Engineering Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.identifier.journalAdvanced Materials
dc.eprint.versionPost-print
dc.contributor.institutionDepartment of Chemical Engineering; Delft University of Technology; Van der Maasweg 9 2629 HZ Delft The Netherlands
dc.contributor.institutionDepartment of Chemistry and Chemical Biology; Baker Laboratory; Cornell University; 259 East Ave NY 14850 USA
dc.contributor.institutionServicios Científico Técnicos; Universidad de Oviedo; Oviedo 33006 Spain
dc.contributor.institutionHeterogene Reaktionen; Max-Planck-Institut für Chemische Engergiekonversion; Stifstrasse 34-36 D-45470 Mülheim an der Ruhr Germany
dc.contributor.institutionDepartment of Biomedical Engineering; University of Groningen and University Medical Center Groningen; Antonius Deusinglaan 1 9713 AV Groningen The Netherlands
dc.contributor.institutionDepartment of Chemical Engineering and Chemistry; Eindhoven University of Technology; P. O. Box 513 5600 MB Eindhoven The Netherlands
dc.contributor.institutionInorganic Chemistry and Catalysis group; Debye Institute for Nanomaterials Science; Utrecht University; Universiteitsweg 99 3584 CG Utrecht The Netherlands
dc.contributor.institutionLaboratory of Organic Chemistry; Wageningen University; Stippeneng 4 6708 WE Wageningen The Netherlands
kaust.personPustovarenko, Alexey
kaust.personBelmabkhout, Youssef
kaust.personDikhtiarenko, Alla
kaust.personEddaoudi, Mohamed
kaust.personGascon, Jorge


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