Thin porphyrin composite membranes with enhanced organic solvent transport
KAUST DepartmentAdvanced Membranes and Porous Materials Research Center
Biological and Environmental Sciences and Engineering (BESE) Division
Chemical Engineering Program
Environmental Science and Engineering Program
Imaging and Characterization Core Lab
Nanofabrication Core Lab
Nanostructured Polymeric Membrane Lab
Physical Science and Engineering (PSE) Division
Water Desalination and Reuse Research Center (WDRC)
Online Publication Date2018-05-01
Print Publication Date2018-10
Permanent link to this recordhttp://hdl.handle.net/10754/627768
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AbstractExtending the stability of polymeric membranes in organic solvents is important for applications in chemical and pharmaceutical industry. Thin-film composite membranes with enhanced solvent permeance are proposed, using porphyrin as a building block. Hybrid polyamide films are formed by interfacial polymerization of 5,10,15,20-(tetra-4-aminophenyl)porphyrin/m-phenylene diamine (MPD) mixtures with trimesoyl chloride. Porphyrin is a non-planar molecule, containing a heterocyclic tetrapyrrole unit. Its incorporation into a polyamide film leads to higher free volume than that of a standard polyamide film. Polyamide films derived from porphyrin and MPD amines with a fixed total amine concentration of 1wt% and various porphyrin/MPD ratios were fabricated and characterized. The porphyrin/MPD polyamide film was complexed with Cu(II), due to the binding capacity of porphyrin to metal ions. By coupling scanning transmission electron microscopy (STEM) with electron energy-loss spectroscopy (EELS), Cu mapping was obtained, revealing the distribution of porphyrin in the interfacial polymerized layer. By using porphyrin as amine-functionalized monomer a membrane with thin selective skin and enhanced solvent transport is obtained, with good dye selectivity in the nanofiltration range. For instance, an ultra-fast hexane permeance, 40-fold increased, was confirmed when using 0.5/0.5 porphyrin/MPD mixtures, instead of only MPD as amine monomer. A rejection of 94.2% Brilliant Blue R (826g/mol) in methanol was measured.
CitationDuong PHH, Anjum DH, Peinemann K-V, Nunes SP (2018) Thin porphyrin composite membranes with enhanced organic solvent transport. Journal of Membrane Science. Available: http://dx.doi.org/10.1016/j.memsci.2018.04.038.
SponsorsThis work was sponsored by King Abdullah University of Science and Technology (KAUST).
JournalJournal of Membrane Science