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    Highly reversible lead-carbon battery anode with lead grafting on the carbon surface

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    pagination_JECHEM_558.pdf
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    Description:
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    Type
    Article
    Authors
    Yin, Jian
    Lin, Nan
    Zhang, Wenli cc
    Lin, Zheqi
    Zhang, Ziqing
    Wang, Yue
    Shi, Jun
    Bao, Jinpeng
    Lin, Haibo
    KAUST Department
    Material Science and Engineering Program
    Physical Science and Engineering (PSE) Division
    Date
    2018-03-27
    Online Publication Date
    2018-03-27
    Print Publication Date
    2018-11
    Permanent link to this record
    http://hdl.handle.net/10754/627477
    
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    Abstract
    A novel C/Pb composite has been successfully prepared by electroless plating to reduce the hydrogen evolution and achieve the high reversibility of the anode of lead-carbon battery (LCB). The deposited lead on the surface of C/Pb composite was found to be uniform and adherent to carbon surface. Because lead has been stuck on the surface of C/Pb composite, the embedded structure suppresses the hydrogen evolution of lead-carbon anode and strengthens the connection between carbon additive and sponge lead. Compared with the blank anode, the lead-carbon anode with C/Pb composite displays excellent charge–discharge reversibility, which is attributed to the good connection between carbon additives and lead that has been stuck on the surface of C/Pb composite during the preparation process. The addition of C/Pb composite maintains a solid anode structure with high specific surface area and power volume, and thereby, it plays a significant role in the highly reversible lead-carbon anode.
    Citation
    Yin J, Lin N, Zhang W, Lin Z, Zhang Z, et al. (2018) Highly reversible lead-carbon battery anode with lead grafting on the carbon surface. Journal of Energy Chemistry. Available: http://dx.doi.org/10.1016/j.jechem.2018.03.002.
    Sponsors
    The research group acknowledges the financial support provided by the National Natural Science Foundation of China (No. 21573093), the National Key Research and Development Program (No. 2017YFB0307501) and Guangdong Innovative and Entrepreneurial Research Team Program (No.2013C092).
    Publisher
    Elsevier BV
    Journal
    Journal of Energy Chemistry
    DOI
    10.1016/j.jechem.2018.03.002
    Additional Links
    https://www.sciencedirect.com/science/article/pii/S2095495617311701
    ae974a485f413a2113503eed53cd6c53
    10.1016/j.jechem.2018.03.002
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division; Material Science and Engineering Program

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