Large Dielectric Constant Enhancement in MXene Percolative Polymer Composites
KAUST DepartmentPhysical Sciences and Engineering (PSE) Division
Materials Science and Engineering Program
Permanent link to this recordhttp://hdl.handle.net/10754/627455
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Abstractnear the percolation limit of about 15.0 wt % MXene loading, which surpasses all previously reported composites made of carbon-based fillers in the same polymer. With up to 10 wt % MXene loading, the dielectric loss of the MXene/P(VDF-TrFE-CFE) composite indicates only an approximately 5-fold increase (from 0.06 to 0.35), while the dielectric constant increased by 25 times over the same composition range. Furthermore, the ratio of permittivity to loss factor of the MXene-polymer composite is superior to that of all previously reported fillers in this same polymer. The dielectric constant enhancement effect is demonstrated to exist in other polymers as well when loaded with MXene. We show that the dielectric constant enhancement is largely due to the charge accumulation caused by the formation of microscopic dipoles at the surfaces between the MXene sheets and the polymer matrix under an external applied electric field.
CitationTu S, Jiang Q, Zhang X, Alshareef HN (2018) Large Dielectric Constant Enhancement in MXene Percolative Polymer Composites. ACS Nano. Available: http://dx.doi.org/10.1021/acsnano.7b08895.
SponsorsResearch reported in this publication is supported by King Abdullah University of Science and Technology (KAUST). The authors would like to thank the Advanced Nanofabrication, Imaging and Characterization Laboratory at KAUST for their excellent assistance.
PublisherAmerican Chemical Society (ACS)
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