High-flux water desalination with interfacial salt sieving effect in nanoporous carbon composite membranes
KAUST DepartmentAdvanced Membranes and Porous Materials Research Center
Chemical Engineering Program
Chemical Science Program
Computer, Electrical and Mathematical Sciences and Engineering (CEMSE) Division
Extreme Computing Research Center
Homogeneous Catalysis Laboratory (HCL)
KAUST Catalysis Center (KCC)
Material Science and Engineering Program
Physical Science and Engineering (PSE) Division
Online Publication Date2018-03-05
Print Publication Date2018-04
Permanent link to this recordhttp://hdl.handle.net/10754/627420
MetadataShow full item record
AbstractFreshwater flux and energy consumption are two important benchmarks for the membrane desalination process. Here, we show that nanoporous carbon composite membranes, which comprise a layer of porous carbon fibre structures grown on a porous ceramic substrate, can exhibit 100% desalination and a freshwater flux that is 3-20 times higher than existing polymeric membranes. Thermal accounting experiments demonstrated that the carbon composite membrane saved over 80% of the latent heat consumption. Theoretical calculations combined with molecular dynamics simulations revealed the unique microscopic process occurring in the membrane. When the salt solution is stopped at the openings to the nanoscale porous channels and forms a meniscus, the vapour can rapidly transport across the nanoscale gap to condense on the permeate side. This process is driven by the chemical potential gradient and aided by the unique smoothness of the carbon surface. The high thermal conductivity of the carbon composite membrane ensures that most of the latent heat is recovered.
CitationChen W, Chen S, Liang T, Zhang Q, Fan Z, et al. (2018) High-flux water desalination with interfacial salt sieving effect in nanoporous carbon composite membranes. Nature Nanotechnology. Available: http://dx.doi.org/10.1038/s41565-018-0067-5.
SponsorsCommercial PTFE membranes and FO membranes were provided by N. Ghaffour and T. Zhang from the KAUST Water Desalination and Reuse Center. Z.L. acknowledges support from KAUST (grant URF/1/1723) and KACST (grant RGC/3/1614). P.S. acknowledges support from KAUST (Special Partnerships Award number UK-C0016 and grant SA-C0040), HKUST (grant SRFI 11/SC02) and the William Mong Institute of Nanoscience and Technology (grant G5537-E).
CollectionsArticles; Advanced Membranes and Porous Materials Research Center; Physical Science and Engineering (PSE) Division; Extreme Computing Research Center; Chemical Science Program; Chemical Engineering Program; Material Science and Engineering Program; KAUST Catalysis Center (KCC); Computer, Electrical and Mathematical Science and Engineering (CEMSE) Division
- Experimental evidence of rapid water transport through carbon nanotubes embedded in polymeric desalination membranes.
- Authors: Lee HD, Kim HW, Cho YH, Park HB
- Issue date: 2014 Jul 9
- Interfacial Ions Sieving for Ultrafast and Complete Desalination through 2D Nanochannel Defined Graphene Composite Membranes.
- Authors: Gong D, Yin Y, Chen H, Guo B, Wu P, Wang Y, Yang Y, Li Z, He Y, Zeng G
- Issue date: 2021 Jun 22
- Atomistic and continuum scale modeling of functionalized graphyne membranes for water desalination.
- Authors: Raju M, Govindaraju PB, van Duin ACT, Ihme M
- Issue date: 2018 Feb 22
- Integrating seawater desalination and wastewater reclamation forward osmosis process using thin-film composite mixed matrix membrane with functionalized carbon nanotube blended polyethersulfone support layer.
- Authors: Choi HG, Son M, Choi H
- Issue date: 2017 Oct
- Enhanced Flux and Electrochemical Cleaning of Silicate Scaling on Carbon Nanotube-Coated Membrane Distillation Membranes Treating Geothermal Brines.
- Authors: Tang L, Iddya A, Zhu X, Dudchenko AV, Duan W, Turchi C, Vanneste J, Cath TY, Jassby D
- Issue date: 2017 Nov 8