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dc.contributor.authorGu, Bin
dc.contributor.authorSun, Chenglin
dc.contributor.authorFettinger, James C.
dc.contributor.authorCasey, William H.
dc.contributor.authorDikhtiarenko, Alla
dc.contributor.authorGascon, Jorge
dc.contributor.authorKoichumanova, Kamila
dc.contributor.authorBabu Sai Sankar Gupta, Karthick
dc.contributor.authorJan Heeres, Hero
dc.contributor.authorHe, Songbo
dc.date.accessioned2018-04-09T07:37:07Z
dc.date.available2018-04-09T07:37:07Z
dc.date.issued2018
dc.identifier.citationGu B, Sun C, Fettinger JC, Casey WH, Dikhtiarenko A, et al. (2018) Synthesis, characterization and properties of a glycol-coordinated ε-Keggin-type Al13 chloride. Chemical Communications. Available: http://dx.doi.org/10.1039/c8cc01363b.
dc.identifier.issn1359-7345
dc.identifier.issn1364-548X
dc.identifier.pmid29623969
dc.identifier.doi10.1039/c8cc01363b
dc.identifier.urihttp://hdl.handle.net/10754/627418
dc.description.abstractHerein we present the first example of a glycol-coordinated ε-Keggin Al13 chloride (gl-ε-Al13), which is the first chelated version since discovery of Al13 in 1960. The molecular structure consists of [AlO4Al12(OH)12(OC2H4OH)12]Cl7·H2O units with chelating mono-anionic ethylene glycol units replacing one bridging and one terminal oxygen site.
dc.description.sponsorshipS. He thanks financial support from National Natural Science Foundation of China (No. 21206161). WHC acknowledges financial support by the NSF Phase-3 CCI, Center for Sustainable Materials Chemistry (NSF CHE-1606982). WHC and JCF thank the National Science Foundation (Grant CHE-1531193) for the dual-source X-ray diffractometer.
dc.publisherRoyal Society of Chemistry (RSC)
dc.relation.urlhttp://pubs.rsc.org/en/content/articlehtml/2018/cc/c8cc01363b
dc.rightsArchived with thanks to Chemical Communications
dc.titleSynthesis, characterization and properties of a glycol-coordinated ε-Keggin-type Al13 chloride
dc.typeArticle
dc.contributor.departmentChemical Engineering Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalChemical Communications
dc.eprint.versionPost-print
dc.contributor.institutionDalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P. R. China.
dc.contributor.institutionDepartment of Chemistry, University of California, Davis, CA 95616, USA.
dc.contributor.institutionFaculty of Science, University of Amsterdam, 1090 GS Amsterdam, The Netherlands.
dc.contributor.institutionLeiden Institute of Chemistry, Leiden University, 2300 RA Leiden, The Netherlands.
dc.contributor.institutionGreen Chemical Reaction Engineering, University of Groningen, 9747 AG Groningen, The Netherlands.
kaust.personDikhtiarenko, Alla
kaust.personGascon, Jorge
dc.relation.issupplementedbyDOI:10.5517/ccdc.csd.cc1ywbms
refterms.dateFOA2019-03-29T00:00:00Z
display.relations<b>Is Supplemented By:</b><br/> <ul><li><i>[Dataset]</i> <br/> Gu, B., Sun, C., Fettinger, J. C., Casey, W. H., Dikhtiarenko, A., Gascon, J., Koichumanova, K., Gupta, K. B. S. S., Heeres, H. J., &amp; He, S. (2018). <i>CCDC 1813736: Experimental Crystal Structure Determination</i> [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC1YWBMS. DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc1ywbms" >10.5517/ccdc.csd.cc1ywbms</a> Handle: <a href="http://hdl.handle.net/10754/664057" >10754/664057</a></a></li></ul>


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