Aqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using Bedford-type palladacycle catalyst
AuthorsGhorpade, Seema Arun
KAUST DepartmentBiological & Organometallic Catalysis Laboratories
Biological and Environmental Sciences and Engineering (BESE) Division
Chemical Science Program
KAUST Catalysis Center (KCC)
KAUST Solar Center (KSC)
Office of the VP
Physical Science and Engineering (PSE) Division
Young Talent Development
KAUST Grant NumberFIC/2010/07
Permanent link to this recordhttp://hdl.handle.net/10754/627385
MetadataShow full item record
AbstractAllylic arylation of cinnamyl acetates with sodium tetraphenylborate using 0.002 mol % of Bedford-type palladacycle catalyst is described. The developed methodology is applicable for wide range of cinnamyl acetates furnishing excellent yields up to 93%. Notably all reactions proceed smoothly under mild reaction conditions in water under air atmosphere.
CitationGhorpade SA, Sawant DN, Renn D, Zernickel A, Du W, et al. (2018) Aqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using a Bedford-type palladacycle catalyst. New Journal of Chemistry. Available: http://dx.doi.org/10.1039/c8nj00660a.
SponsorsThe author Seema Arun Ghorpade is thankful to the Institute of Chemical Technology, Matunga, Mumbai and Department of Science and Technology (DST) India for providing DST INSPIRE Senior Research Fellowship (IF110631). This work was supported by the King Abdullah University of Science and Technology (KAUST baseline funding and GCR grant FIC/2010/07). Authors are gratefully acknowledging support from King Abdullah University of Science and Technology (KAUST), Saudi Arabia.
PublisherRoyal Society of Chemistry (RSC)
JournalNew Journal of Chemistry