Aqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using Bedford-type palladacycle catalyst
Type
ArticleAuthors
Ghorpade, Seema ArunSawant, Dinesh N
Renn, Dominik
Zernickel, Anna
Du, Weiyuan
Sekar, Nethi
Eppinger, Jörg
KAUST Department
Biological and Environmental Sciences and Engineering (BESE) DivisionBioscience Program
KAUST Solar Center (KSC)
Physical Sciences and Engineering (PSE) Division
Chemical Science Program
KAUST Catalysis Center (KCC)
KAUST Grant Number
FIC/2010/07Date
2018-03-19Metadata
Show full item recordAbstract
Allylic arylation of cinnamyl acetates with sodium tetraphenylborate using 0.002 mol % of Bedford-type palladacycle catalyst is described. The developed methodology is applicable for wide range of cinnamyl acetates furnishing excellent yields up to 93%. Notably all reactions proceed smoothly under mild reaction conditions in water under air atmosphere.Citation
Ghorpade SA, Sawant DN, Renn D, Zernickel A, Du W, et al. (2018) Aqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using a Bedford-type palladacycle catalyst. New Journal of Chemistry. Available: http://dx.doi.org/10.1039/c8nj00660a.Sponsors
The author Seema Arun Ghorpade is thankful to the Institute of Chemical Technology, Matunga, Mumbai and Department of Science and Technology (DST) India for providing DST INSPIRE Senior Research Fellowship (IF110631). This work was supported by the King Abdullah University of Science and Technology (KAUST baseline funding and GCR grant FIC/2010/07). Authors are gratefully acknowledging support from King Abdullah University of Science and Technology (KAUST), Saudi Arabia.Publisher
Royal Society of Chemistry (RSC)Journal
New Journal of ChemistryISSN
1144-05461369-9261