Aqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using Bedford-type palladacycle catalyst
Type
ArticleAuthors
Ghorpade, Seema ArunSawant, Dinesh
Renn, Dominik
Zernickel, Anna

du, weiyuan

Sekar, Nethi
Eppinger, Jörg

KAUST Department
Biological & Organometallic Catalysis LaboratoriesBiological and Environmental Sciences and Engineering (BESE) Division
Bioscience Program
Chemical Science Program
KAUST Catalysis Center (KCC)
KAUST Solar Center (KSC)
Office of the VP
Physical Science and Engineering (PSE) Division
Young Talent Development
KAUST Grant Number
FIC/2010/07Date
2018Permanent link to this record
http://hdl.handle.net/10754/627385
Metadata
Show full item recordAbstract
Allylic arylation of cinnamyl acetates with sodium tetraphenylborate using 0.002 mol % of Bedford-type palladacycle catalyst is described. The developed methodology is applicable for wide range of cinnamyl acetates furnishing excellent yields up to 93%. Notably all reactions proceed smoothly under mild reaction conditions in water under air atmosphere.Citation
Ghorpade SA, Sawant DN, Renn D, Zernickel A, Du W, et al. (2018) Aqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using a Bedford-type palladacycle catalyst. New Journal of Chemistry. Available: http://dx.doi.org/10.1039/c8nj00660a.Sponsors
The author Seema Arun Ghorpade is thankful to the Institute of Chemical Technology, Matunga, Mumbai and Department of Science and Technology (DST) India for providing DST INSPIRE Senior Research Fellowship (IF110631). This work was supported by the King Abdullah University of Science and Technology (KAUST baseline funding and GCR grant FIC/2010/07). Authors are gratefully acknowledging support from King Abdullah University of Science and Technology (KAUST), Saudi Arabia.Publisher
Royal Society of Chemistry (RSC)Journal
New Journal of Chemistryae974a485f413a2113503eed53cd6c53
10.1039/c8nj00660a