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    Aqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using Bedford-type palladacycle catalyst

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    Type
    Article
    Authors
    Ghorpade, Seema Arun
    Sawant, Dinesh
    Renn, Dominik
    Zernickel, Anna cc
    du, weiyuan cc
    Sekar, Nethi
    Eppinger, Jörg cc
    KAUST Department
    Biological & Organometallic Catalysis Laboratories
    Biological and Environmental Sciences and Engineering (BESE) Division
    Bioscience Program
    Chemical Science Program
    KAUST Catalysis Center (KCC)
    KAUST Solar Center (KSC)
    Office of the VP
    Physical Science and Engineering (PSE) Division
    Young Talent Development
    KAUST Grant Number
    FIC/2010/07
    Date
    2018
    Permanent link to this record
    http://hdl.handle.net/10754/627385
    
    Metadata
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    Abstract
    Allylic arylation of cinnamyl acetates with sodium tetraphenylborate using 0.002 mol % of Bedford-type palladacycle catalyst is described. The developed methodology is applicable for wide range of cinnamyl acetates furnishing excellent yields up to 93%. Notably all reactions proceed smoothly under mild reaction conditions in water under air atmosphere.
    Citation
    Ghorpade SA, Sawant DN, Renn D, Zernickel A, Du W, et al. (2018) Aqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using a Bedford-type palladacycle catalyst. New Journal of Chemistry. Available: http://dx.doi.org/10.1039/c8nj00660a.
    Sponsors
    The author Seema Arun Ghorpade is thankful to the Institute of Chemical Technology, Matunga, Mumbai and Department of Science and Technology (DST) India for providing DST INSPIRE Senior Research Fellowship (IF110631). This work was supported by the King Abdullah University of Science and Technology (KAUST baseline funding and GCR grant FIC/2010/07). Authors are gratefully acknowledging support from King Abdullah University of Science and Technology (KAUST), Saudi Arabia.
    Publisher
    Royal Society of Chemistry (RSC)
    Journal
    New Journal of Chemistry
    DOI
    10.1039/c8nj00660a
    Additional Links
    http://pubs.rsc.org/en/Content/ArticleLanding/2018/NJ/C8NJ00660A#!divAbstract
    ae974a485f413a2113503eed53cd6c53
    10.1039/c8nj00660a
    Scopus Count
    Collections
    Articles; Biological and Environmental Sciences and Engineering (BESE) Division; Bioscience Program; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC); KAUST Solar Center (KSC)

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