Aqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using Bedford-type palladacycle catalyst

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Type
Article
Authors
Ghorpade, Seema Arun
Sawant, Dinesh
Renn, Dominik
Zernickel, Anna cc
du, weiyuan cc
Sekar, Nethi
Eppinger, Jörg cc
KAUST Department
Biological & Organometallic Catalysis Laboratories
Biological and Environmental Sciences and Engineering (BESE) Division
Bioscience Program
Chemical Science Program
KAUST Catalysis Center (KCC)
KAUST Solar Center (KSC)
Office of the VP
Physical Science and Engineering (PSE) Division
Young Talent Development
KAUST Grant Number
FIC/2010/07
Date
2018
Permanent link to this record
http://hdl.handle.net/10754/627385

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Abstract
Allylic arylation of cinnamyl acetates with sodium tetraphenylborate using 0.002 mol % of Bedford-type palladacycle catalyst is described. The developed methodology is applicable for wide range of cinnamyl acetates furnishing excellent yields up to 93%. Notably all reactions proceed smoothly under mild reaction conditions in water under air atmosphere.
Citation
Ghorpade SA, Sawant DN, Renn D, Zernickel A, Du W, et al. (2018) Aqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using a Bedford-type palladacycle catalyst. New Journal of Chemistry. Available: http://dx.doi.org/10.1039/c8nj00660a.
Sponsors
The author Seema Arun Ghorpade is thankful to the Institute of Chemical Technology, Matunga, Mumbai and Department of Science and Technology (DST) India for providing DST INSPIRE Senior Research Fellowship (IF110631). This work was supported by the King Abdullah University of Science and Technology (KAUST baseline funding and GCR grant FIC/2010/07). Authors are gratefully acknowledging support from King Abdullah University of Science and Technology (KAUST), Saudi Arabia.
Publisher
Royal Society of Chemistry (RSC)
Journal
New Journal of Chemistry
DOI
10.1039/c8nj00660a
Additional Links
http://pubs.rsc.org/en/Content/ArticleLanding/2018/NJ/C8NJ00660A#!divAbstract
Collections
Articles; Biological and Environmental Sciences and Engineering (BESE) Division; Bioscience Program; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC); KAUST Solar Center (KSC)