Aqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using Bedford-type palladacycle catalyst

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Type
Article
Authors
Ghorpade, Seema Arun
Sawant, Dinesh N
Renn, Dominik
Zernickel, Anna cc
Du, Weiyuan
Sekar, Nethi
Eppinger, Jörg cc
KAUST Department
Biological and Environmental Sciences and Engineering (BESE) Division
Bioscience Program
KAUST Solar Center (KSC)
Physical Sciences and Engineering (PSE) Division
Chemical Science Program
KAUST Catalysis Center (KCC)
KAUST Grant Number
FIC/2010/07
Date
2018-03-19

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Abstract
Allylic arylation of cinnamyl acetates with sodium tetraphenylborate using 0.002 mol % of Bedford-type palladacycle catalyst is described. The developed methodology is applicable for wide range of cinnamyl acetates furnishing excellent yields up to 93%. Notably all reactions proceed smoothly under mild reaction conditions in water under air atmosphere.
Citation
Ghorpade SA, Sawant DN, Renn D, Zernickel A, Du W, et al. (2018) Aqueous protocol for allylic arylation of cinnamyl acetates with sodium tetraphenylborate using a Bedford-type palladacycle catalyst. New Journal of Chemistry. Available: http://dx.doi.org/10.1039/c8nj00660a.
Sponsors
The author Seema Arun Ghorpade is thankful to the Institute of Chemical Technology, Matunga, Mumbai and Department of Science and Technology (DST) India for providing DST INSPIRE Senior Research Fellowship (IF110631). This work was supported by the King Abdullah University of Science and Technology (KAUST baseline funding and GCR grant FIC/2010/07). Authors are gratefully acknowledging support from King Abdullah University of Science and Technology (KAUST), Saudi Arabia.
Publisher
Royal Society of Chemistry (RSC)
Journal
New Journal of Chemistry
ISSN
1144-0546
1369-9261
DOI
10.1039/c8nj00660a
Handle URI
http://hdl.handle.net/10754/627385
Additional Links
http://pubs.rsc.org/en/Content/ArticleLanding/2018/NJ/C8NJ00660A#!divAbstract
Collections
Articles; Bioscience Program; Physical Sciences and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC); KAUST Solar Center (KSC); Biological and Environmental Sciences and Engineering (BESE) Division