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dc.contributor.authorAguilar Tapia, Antonio
dc.contributor.authorOuld-Chikh, Samy
dc.contributor.authorLahera, Eric
dc.contributor.authorPrat, Alain
dc.contributor.authorDelnet, William
dc.contributor.authorProux, Olivier
dc.contributor.authorKieffer, Isabelle
dc.contributor.authorBasset, Jean-Marie
dc.contributor.authorTakanabe, Kazuhiro
dc.contributor.authorHazemann, Jean-Louis
dc.date.accessioned2018-04-01T08:20:26Z
dc.date.available2018-04-01T08:20:26Z
dc.date.issued2018-03-22
dc.identifier.citationAguilar-Tapia A, Ould-Chikh S, Lahera E, Prat A, Delnet W, et al. (2018) A new high temperature reactor for operando XAS: Application for the dry reforming of methane over Ni/ZrO2 catalyst. Review of Scientific Instruments 89: 035109. Available: http://dx.doi.org/10.1063/1.4998929.
dc.identifier.issn0034-6748
dc.identifier.issn1089-7623
dc.identifier.doi10.1063/1.4998929
dc.identifier.urihttp://hdl.handle.net/10754/627383
dc.description.abstractThe construction of a high-temperature reaction cell for operando X-ray absorption spectroscopy characterization is reported. A dedicated cell was designed to operate as a plug-flow reactor using powder samples requiring gas flow and thermal treatment at high temperatures. The cell was successfully used in the reaction of dry reforming of methane (DRM). We present X-ray absorption results in the fluorescence detection mode on a 0.4 wt. % Ni/ZrO2 catalyst under realistic conditions at 750 °C, reproducing the conditions used for a conventional dynamic microreactor for the DRM reaction. The setup includes a gas distribution system that can be fully remotely operated. The reaction cell offers the possibility of transmission and fluorescence detection modes. The complete setup dedicated to the study of catalysts is permanently installed on the Collaborating Research Groups French Absorption spectroscopy beamline in Material and Environmental sciences (CRG-FAME) and French Absorption spectroscopy beamline in Material and Environmental sciences at Ultra-High Dilution (FAME-UHD) beamlines (BM30B and BM16) at the European Synchrotron Radiation Facility in Grenoble, France.
dc.description.sponsorshipWe thank Dr. Bedour AlSabban for the assistance with the preparation method of the sample.
dc.publisherAIP Publishing
dc.relation.urlhttps://aip.scitation.org/doi/10.1063/1.4998929
dc.rightsThis article may be downloaded for personal use only. Any other use requires prior permission of the author and AIP Publishing. The following article appeared in Review of Scientific Instruments and may be found at http://doi.org/10.1063/1.4998929.
dc.subjectMaterials
dc.subjectPhysics of gases
dc.subjectMetals
dc.subjectRadiation by moving charges
dc.subjectSynchrotron radiation
dc.subjectMaterials treatment
dc.subjectGeneral physics
dc.subjectMetallurgy
dc.subjectOrganic compounds
dc.subjectMaterials science
dc.titleA new high temperature reactor for operando XAS: Application for the dry reforming of methane over Ni/ZrO2 catalyst
dc.typeArticle
dc.contributor.departmentCatalysis for Energy Conversion (CatEC)
dc.contributor.departmentChemical Science Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalReview of Scientific Instruments
dc.eprint.versionPublisher's Version/PDF
dc.contributor.institutionInstitut Néel, UPR 2940 CNRS–Université Grenoble Alpes, F-38000 Grenoble, France
dc.contributor.institutionOSUG, UMS 832 CNRS-Université Grenoble Alpes, F-38041 Grenoble, France
kaust.personAguilar Tapia, Antonio
kaust.personOuld-Chikh, Samy
kaust.personBasset, Jean-Marie
kaust.personTakanabe, Kazuhiro
refterms.dateFOA2019-03-22T00:00:00Z
dc.date.published-online2018-03-22
dc.date.published-print2018-03


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