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    High accuracy line positions of the ν 1 fundamental band of 14 N 2 16 O

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    1-s2.0-S002240731830058X-main.pdf
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    Type
    Article
    Authors
    Alsaif, Bidoor
    Lamperti, Marco cc
    Gatti, Davide cc
    Laporta, Paolo
    Fermann, Martin
    Farooq, Aamir cc
    Lyulin, Oleg
    Campargue, Alain
    Marangoni, Marco
    KAUST Department
    Chemical Kinetics & Laser Sensors Laboratory
    Clean Combustion Research Center
    Computer, Electrical and Mathematical Sciences and Engineering (CEMSE) Division
    Electrical Engineering Program
    Mechanical Engineering Program
    Physical Science and Engineering (PSE) Division
    Date
    2018-03-08
    Online Publication Date
    2018-03-08
    Print Publication Date
    2018-05
    Permanent link to this record
    http://hdl.handle.net/10754/627327
    
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    Abstract
    The ν1 fundamental band of N2O is examined by a novel spectrometer that relies on the frequency locking of an external-cavity quantum cascade laser around 7.8 μm to a near-infrared Tm:based frequency comb at 1.9 μm. Due to the large tunability, nearly 70 lines in the 1240 – 1310 cm−1 range of the ν1 band of N2O, from P(40) to R(31), are for the first time measured with an absolute frequency calibration and an uncertainty from 62 to 180 kHz, depending on the line. Accurate values of the spectroscopic constants of the upper state are derived from a fit of the line centers (rms ≈ 4.8 × 10−6 cm−1 or 144 kHz). The ν1 transitions presently measured in a Doppler regime validate high accuracy predictions based on sub-Doppler measurements of the ν3 and ν3-ν1 transitions.
    Citation
    AlSaif B, Lamperti M, Gatti D, Laporta P, Fermann M, et al. (2018) High accuracy line positions of the ν 1 fundamental band of 14 N 2 16 O. Journal of Quantitative Spectroscopy and Radiative Transfer. Available: http://dx.doi.org/10.1016/j.jqsrt.2018.03.005.
    Publisher
    Elsevier BV
    Journal
    Journal of Quantitative Spectroscopy and Radiative Transfer
    DOI
    10.1016/j.jqsrt.2018.03.005
    Additional Links
    http://www.sciencedirect.com/science/article/pii/S002240731830058X
    ae974a485f413a2113503eed53cd6c53
    10.1016/j.jqsrt.2018.03.005
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division; Electrical and Computer Engineering Program; Mechanical Engineering Program; Clean Combustion Research Center; Computer, Electrical and Mathematical Science and Engineering (CEMSE) Division

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