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    Synthesis and immobilization of polystyreneb-polyvinyltriethoxysilane micelles

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    Type
    Article
    Authors
    Zhu, Saisai
    Zhu, Hui
    Xia, Ru
    Feng, Xiaoshuang
    Chen, Peng
    Qian, Jiasheng
    Cao, Ming
    Yang, Bin cc
    Miao, Jibin
    Su, Lifen
    Song, Changjiang
    KAUST Department
    Physical Science and Engineering (PSE) Division
    Date
    2018-01-31
    Online Publication Date
    2018-01-31
    Print Publication Date
    2018-02
    Permanent link to this record
    http://hdl.handle.net/10754/627280
    
    Metadata
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    Abstract
    Diblock copolymers polystyrene-block-polyvinyltriethoxysilane (PS-b-PVTES) were synthesized via atom transfer radical polymerization (ATRP), which self-assembled into spherical micelles in solvent of THF-methanol mixtures. The self-assembled micelles were immobilized by cross-linking reaction of VTES in a shell layer of micelles. The chemical structures of block copolymers and morphology of micelles were characterized in detail. It was found that the size of immobilized micelles was strongly affected by the copolymer concentration, composition of mixture solvent, and block ratios.
    Citation
    Zhu S, Zhu H, Xia R, Feng X, Chen P, et al. (2018) Synthesis and immobilization of polystyreneb-polyvinyltriethoxysilane micelles. Journal of Wuhan University of Technology-Mater Sci Ed 33: 221–225. Available: http://dx.doi.org/10.1007/s11595-018-1809-9.
    Sponsors
    Funded by the National Natural Science Foundation of China (Nos. 51403001, 20804001, 20974001, 21174001, 51273001), the Research Fund for the Doctoral Program of Higher Education of China (No.20113401110003), “211 Project” and “Incubation Fund for Excellent Young Researcher” of Anhui University
    Publisher
    Springer Nature
    Journal
    Journal of Wuhan University of Technology-Mater. Sci. Ed.
    DOI
    10.1007/s11595-018-1809-9
    Additional Links
    http://link.springer.com/article/10.1007/s11595-018-1809-9
    ae974a485f413a2113503eed53cd6c53
    10.1007/s11595-018-1809-9
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division

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