Nitrogen atom transfer mediated by a new PN3P-pincer nickel core via a putative nitrido nickel intermediate

Abstract
A 2nd generation PN3P-pincer azido nickel complex (PN3P)Ni(N3) reacts with isocyanides to afford monosubstituted carbodiimides under irradiation, presumably via a transient nitrido intermediate. The resulting species can further generate unsymmetrical carboddimides and the PN3P nickel halide complex, accomplishing a synthetic cycle for a complete nitrogen atom transfer reaction.

Citation
Yao C, Wang X, Huang K-W (2018) Nitrogen atom transfer mediated by a new PN3P-pincer nickel core via a putative nitrido nickel intermediate. Chemical Communications. Available: http://dx.doi.org/10.1039/c7cc09804a.

Acknowledgements
We acknowledge support from King Abdullah University of Science and Technology (KAUST).

Publisher
Royal Society of Chemistry (RSC)

Journal
Chemical Communications

DOI
10.1039/c7cc09804a

PubMed ID
29461556

Additional Links
http://pubs.rsc.org/en/content/articlehtml/2018/cc/c7cc09804a

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