Nitrogen atom transfer mediated by a new PN3P-pincer nickel core via a putative nitrido nickel intermediate

Type
Article
Authors
Yao, Changguang
Wang, Xiufang
Huang, Kuo-Wei cc
KAUST Department
Chemical Science Program
Homogeneous Catalysis Laboratory (HCL)
KAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Date
2018
Permanent link to this record
http://hdl.handle.net/10754/627263

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Abstract
A 2nd generation PN3P-pincer azido nickel complex (PN3P)Ni(N3) reacts with isocyanides to afford monosubstituted carbodiimides under irradiation, presumably via a transient nitrido intermediate. The resulting species can further generate unsymmetrical carboddimides and the PN3P nickel halide complex, accomplishing a synthetic cycle for a complete nitrogen atom transfer reaction.
Citation
Yao C, Wang X, Huang K-W (2018) Nitrogen atom transfer mediated by a new PN3P-pincer nickel core via a putative nitrido nickel intermediate. Chemical Communications. Available: http://dx.doi.org/10.1039/c7cc09804a.
Sponsors
We acknowledge support from King Abdullah University of Science and Technology (KAUST).
Publisher
Royal Society of Chemistry (RSC)
Journal
Chemical Communications
DOI
10.1039/c7cc09804a
PubMed ID
29461556
Additional Links
http://pubs.rsc.org/en/content/articlehtml/2018/cc/c7cc09804a
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Articles; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)