Revealing Transient Concentration of CO2 in a Mixed Matrix Membrane by IR Microimaging and Molecular Modeling
Type
ArticleAuthors
Hwang, SeungtaikSemino, Rocio
Seoane, Beatriz
Zahan, Marufa
Chmelik, Christian
Valiullin, Rustem
Bertmer, Marko
Haase, Jürgen
Kapteijn, Freek

Gascon, Jorge

Maurin, Guillaume

Kärger, Jörg
KAUST Department
Chemical Engineering ProgramKAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Date
2018-03-25Online Publication Date
2018-03-25Print Publication Date
2018-04-23Permanent link to this record
http://hdl.handle.net/10754/627202
Metadata
Show full item recordAbstract
Through IR microimaging the spatially and temporally resolved development of the CO2 concentration in a ZIF-8@6FDA-DAM mixed matrix membrane was visualized during transient adsorption. By recording the evolution of the CO2 concentration, it is observed that the CO2 molecules propagate from the ZIF-8 filler, which acts as a transportCitation
Hwang S, Semino R, Seoane B, Zahan M, Chmelik C, et al. (2018) Revealing Transient Concentration of CO2 in a Mixed Matrix Membrane by IR Microimaging and Molecular Modeling. Angewandte Chemie International Edition. Available: http://dx.doi.org/10.1002/anie.201713160.Sponsors
The research leading to these results has received funding from the European Community Seventh Program (FP7/2007-2013) under Grant 608490 (project M4CO2). IR microimaging was ensured by German Science Foundation via the grants HA 1893/17-1 and KA 953/35-1. G.M. thanks Institut Universitaire de France for its support. The authors thank J. Caro (Hannover) for stimulating discussions and synthesizing the large ZIF-8 crystals.Publisher
Wiley-BlackwellAdditional Links
http://onlinelibrary.wiley.com/doi/10.1002/anie.201713160/abstractae974a485f413a2113503eed53cd6c53
10.1002/anie.201713160