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dc.contributor.authorMaity, Niladri
dc.contributor.authorBarman, Samir
dc.contributor.authorAbou-Hamad, Edy
dc.contributor.authorD’Elia, Valerio
dc.contributor.authorBasset, Jean-Marie
dc.date.accessioned2018-02-22T10:34:40Z
dc.date.available2018-02-22T10:34:40Z
dc.date.issued2018
dc.identifier.citationMaity N, Barman S, Abou-Hamad edy, D’Elia V, Basset J-M (2018) Clean Chlorination of Silica Surfaces by a Single-site Substitution Approach. Dalton Transactions. Available: http://dx.doi.org/10.1039/c8dt00186c.
dc.identifier.issn1477-9226
dc.identifier.issn1477-9234
dc.identifier.pmid29488534
dc.identifier.doi10.1039/c8dt00186c
dc.identifier.urihttp://hdl.handle.net/10754/627165
dc.description.abstractA chlorination method for the selective substitution of well-defined isolated silanol groups of the silica surface has been developed using the catalytic Appel reaction. Spectroscopic analysis, complemented by elemental microanalysis studies, reveals that a quantitative chlorination could be achieved with highly dehydroxylated silica materials that exclusively possess non-hydrogen bonded silanol groups. The employed method did not leave any carbon or phosphorous residue on the silica surface and can be regarded as a promising tool for the future functionalization of metal oxide surfaces.
dc.description.sponsorshipThe research was supported by the King Abdullah University of Science and Technology. V.D.E. thanks the Thailand Research Fund (Grant No. RSA6080059) for supporting this research.
dc.publisherRoyal Society of Chemistry (RSC)
dc.relation.urlhttp://pubs.rsc.org/en/Content/ArticleLanding/2018/DT/C8DT00186C#!divAbstract
dc.rightsArchived with thanks to Dalton Transactions
dc.titleClean Chlorination of Silica Surfaces by a Single-site Substitution Approach
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentImaging and Characterization Core Lab
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentNMR
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalDalton Transactions
dc.eprint.versionPost-print
dc.contributor.institutionDepartment of Chemistry, Indira Gandhi Institute of Technology, Sarang, Dhenkanal, Odisha-759146, India.
dc.contributor.institutionDepartment of Materials Science and Engineering, School of Molecular Science and Engineering, Vidyasirimedhi Institute of Science and Technology (VISTEC), 21210, Payupnai, WangChan, Rayong, Thailand.
kaust.personMaity, Niladri
kaust.personBarman, Samir
kaust.personAbou-Hamad, Edy
kaust.personD'Elia, Valerio
kaust.personBasset, Jean-Marie


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