Show simple item record

dc.contributor.authorArslan, Mustafa*
dc.contributor.authorCem Bicak, Tugrul*
dc.contributor.authorPulido, Bruno*
dc.contributor.authorNunes, Suzana Pereira*
dc.contributor.authorYagci, Yusuf*
dc.date.accessioned2018-02-13T13:43:19Z
dc.date.available2018-02-13T13:43:19Z
dc.date.issued2018-02-08en
dc.identifier.citationArslan M, Cem Bicak T, Pulido B, Nunes SP, Yagci Y (2018) Post Modification of Acetylene Functional Poly(oxindole biphenylylene) by Photoinduced CuAAC. European Polymer Journal. Available: http://dx.doi.org/10.1016/j.eurpolymj.2018.02.009.en
dc.identifier.issn0014-3057en
dc.identifier.doi10.1016/j.eurpolymj.2018.02.009en
dc.identifier.urihttp://hdl.handle.net/10754/627125
dc.description.abstractA novel strategy to obtain side chain modified poly(oxindole biphenylylene) (POXI) by photoinduced copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) click reaction is described. In the first step, an alkyne-functionalized poly(oxindolebiphenylylene) (POXI-alkyne) is synthesized by superacid-catalyzed condensation of isatin with aromatic hydrocarbons. Subsequently, poly(ethylene glycol) methyl ether (Me-PEG), 1-pyrenemethanol (Py-OH) and 1,3-dibromopropane (DBP) are functionalized by azide groups via simple nucleophilic substitution reaction. Visible-light-induced CuAAC reaction between POXI-alkyne and the corresponding azide functionalized click components employing dibenzoyldiethylgermane (DBDEG) as photoactivator resulted in the formation of POXI-PEG, POXI-Py and insoluble network, respectively. Successful modification of POXI was confirmed by the spectral, (1H NMR, FT-IR, Fluorescence), chromatographic (GPC) and thermal (DSC) investigations.en
dc.description.sponsorshipThe authors would like to thank Istanbul Technical University, Research Fund, and King Abdullah University of Science and Technology (KAUST) for financial support.en
dc.publisherElsevier BVen
dc.relation.urlhttps://www.sciencedirect.com/science/article/pii/S001430571732013Xen
dc.rightsNOTICE: this is the author’s version of a work that was accepted for publication in European Polymer Journal. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in European Polymer Journal, [, , (2018-02-08)] DOI: 10.1016/j.eurpolymj.2018.02.009 . © 2018. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/en
dc.subjectPhoto-induced CuAACen
dc.subjectgraftingen
dc.subjectpoly(oxindolebiphenylylene)en
dc.subjectpoly(ethylene glycolen
dc.subjectpyreneen
dc.titlePost Modification of Acetylene Functional Poly(oxindole biphenylylene) by Photoinduced CuAACen
dc.typeArticleen
dc.contributor.departmentBiological and Environmental Sciences and Engineering (BESE) Division*
dc.contributor.departmentEnvironmental Science and Engineering Program*
dc.identifier.journalEuropean Polymer Journalen
dc.eprint.versionPost-printen
dc.contributor.institutionKirklareli University, Faculty of Science and Letters, Department of Chemistry, 39000, Kirklareli, Turkey*
dc.contributor.institutionIstanbul Technical University, Faculty of Science and Letters, Department of Chemistry, Maslak, 34469, Istanbul, Turkey*
kaust.authorPulido, Bruno*
kaust.authorNunes, Suzana Pereira*


Files in this item

Thumbnail
Name:
1-s2.0-S001430571732013X-main.pdf
Size:
1.265Mb
Format:
PDF
Description:
Accepted Manuscript
Embargo End Date:
2020-02-08
Thumbnail
Name:
1-s2.0-S001430571732013X-fx1.jpg
Size:
24.28Kb
Format:
JPEG image
Description:
Graphical abstract

This item appears in the following Collection(s)

Show simple item record