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dc.contributor.authorLi, Hui
dc.contributor.authorSun, Ying
dc.contributor.authorYuan, Zhong-Yong
dc.contributor.authorZhu, Yun-Pei
dc.contributor.authorMa, Tianyi
dc.date.accessioned2018-02-07T07:02:29Z
dc.date.available2018-02-07T07:02:29Z
dc.date.issued2018-02-22
dc.identifier.citationLi H, Sun Y, Yuan Z-Y, Zhu Y-P, Ma T (2018) Titanium-Phosphonate-Based Metal-Organic Frameworks with Hierarchical Porosity for Enhanced Photocatalytic Hydrogen Evolution. Angewandte Chemie International Edition. Available: http://dx.doi.org/10.1002/anie.201712925.
dc.identifier.issn1433-7851
dc.identifier.doi10.1002/anie.201712925
dc.identifier.doi10.1002/ange.201712925
dc.identifier.urihttp://hdl.handle.net/10754/627071
dc.description.abstractPhotocatalytic hydrogen production is crucial for solar-to-chemical conversion process, wherein high-efficiency photocatalysts lie in the heart of this area. Herein a new photocatalyst of hierarchically mesoporous titanium-phosphonate-based metal-organic frameworks, featuring well-structured spheres, periodic mesostructure and large secondary mesoporosity, are rationally designed with the complex of polyelectrolyte and cathodic surfactant serving as the template. The well-structured hierarchical porosity and homogeneously incorporated phosphonate groups can favor the mass transfer and strong optical absorption during the photocatalytic reactions. Correspondingly, the titanium phosphonates exhibit significantly improved photocatalytic hydrogen evolution rate along with impressive stability. This work can provide more insights into designing advanced photocatalysts for energy conversion and render a tunable platform in photoelectrochemical field.
dc.description.sponsorshipThis work was supported by Australian Research Council (ARC) Discovery Early Career Researcher Award (DE150101306) and Linkage Project (LP160100927).
dc.publisherWiley
dc.relation.urlhttp://onlinelibrary.wiley.com/doi/10.1002/anie.201712925/abstract
dc.rightsThis is the peer reviewed version of the following article: Titanium-Phosphonate-Based Metal-Organic Frameworks with Hierarchical Porosity for Enhanced Photocatalytic Hydrogen Evolution, which has been published in final form at http://doi.org/10.1002/anie.201712925. This article may be used for non-commercial purposes in accordance With Wiley Terms and Conditions for self-archiving.
dc.subjectphotocatalysis
dc.subjectMetal-organic framework
dc.subjectHierarchical Porosity
dc.subjectMetal Phosphonate
dc.titleTitanium-Phosphonate-Based Metal-Organic Frameworks with Hierarchical Porosity for Enhanced Photocatalytic Hydrogen Evolution
dc.typeArticle
dc.contributor.departmentKing Abdullah University of Science and Technology (KAUST); Thuwal SAUDI ARABIA
dc.identifier.journalAngewandte Chemie
dc.eprint.versionPost-print
dc.contributor.institutionLiaoning University; 85 Chongshan Road Liaoning CHINA
dc.contributor.institutionLiaoning University; 85 Chongshan Road Shenyang CHINA
dc.contributor.institutionNankai University; School of Materials Science and Engineering; 94 Weijin Road 300071 Tianjin CHINA
dc.contributor.institutionUniversity of Newcastle; Discipline of Chemistry, School of Environmental and life sciences; Room C114, NIER Block C Building The University of Newcastle (UON) University Drive 2308 Callaghan AUSTRALIA
kaust.personZhu, Yun-Pei
refterms.dateFOA2019-01-31T00:00:00Z
dc.date.published-online2018-02-22
dc.date.published-print2018-03-12


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