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dc.contributor.authorTowsif Abtab, Sk Md
dc.contributor.authorAlezi, Dalal
dc.contributor.authorBhatt, Prashant
dc.contributor.authorShkurenko, Aleksander
dc.contributor.authorBelmabkhout, Youssef
dc.contributor.authorAggarwal, Himanshu
dc.contributor.authorWeselinski, Lukasz Jan
dc.contributor.authorAlsadun, Norah Sadun
dc.contributor.authorSamin, Umer
dc.contributor.authorHedhili, Mohamed N.
dc.contributor.authorEddaoudi, Mohamed
dc.date.accessioned2018-02-01T07:25:01Z
dc.date.available2018-02-01T07:25:01Z
dc.date.issued2018-01-11
dc.identifier.citationTowsif Abtab SM, Alezi D, Bhatt PM, Shkurenko A, Belmabkhout Y, et al. (2018) Reticular Chemistry in Action: A Hydrolytically Stable MOF Capturing Twice Its Weight in Adsorbed Water. Chem 4: 94–105. Available: http://dx.doi.org/10.1016/j.chempr.2017.11.005.
dc.identifier.issn2451-9294
dc.identifier.doi10.1016/j.chempr.2017.11.005
dc.identifier.urihttp://hdl.handle.net/10754/626981
dc.description.abstractSummary Hydrolytically stable adsorbents, with notable water uptake, are of prime importance and offer great potential for many water-adsorption-related applications. Nevertheless, deliberate construction of tunable porous solids with high porosity and high stability remains challenging. Here, we present the successful deployment of reticular chemistry to address this demand: we constructed Cr-soc-MOF-1, a chemically and hydrolytically stable chromium-based metal-organic framework (MOF) with underlying soc topology. Prominently, Cr-soc-MOF-1 offers the requisite thermal and chemical stability concomitant with unique adsorption properties, namely extraordinary high porosity (apparent surface area of 4,549 m2/g) affording a water vapor uptake of 1.95 g/g at 70% relative humidity. This exceptional water uptake is maintained over more than 100 adsorption-desorption cycles. Markedly, the adsorbed water can be fully desorbed by just the simple reduction of the relative humidity at 25°C. Cr-soc-MOF-1 offers great potential for use in applications pertaining to water vapor control in enclosed and confined spaces and dehumidification.
dc.description.sponsorshipResearch reported in this publication was fully supported by the King Abdullah University of Science and Technology.
dc.publisherElsevier BV
dc.relation.urlhttp://www.sciencedirect.com/science/article/pii/S2451929417304734
dc.subjectSDG7: Affordable and clean energy
dc.subjectSDG12: Responsible consumption and production
dc.titleReticular Chemistry in Action: A Hydrolytically Stable MOF Capturing Twice Its Weight in Adsorbed Water
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentChemical Engineering Program
dc.contributor.departmentChemical Science Program
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)
dc.contributor.departmentImaging and Characterization Core Lab
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.contributor.departmentSurface Science
dc.identifier.journalChem
kaust.personTowsif Abtab, Sk Md
kaust.personAlezi, Dalal
kaust.personBhatt, Prashant
kaust.personShkurenko, Aleksander
kaust.personBelmabkhout, Youssef
kaust.personAggarwal, Himanshu
kaust.personWeselinski, Lukasz Jan
kaust.personAlsadun, Norah Sadun
kaust.personSamin, Umer
kaust.personHedhili, Mohamed N.
kaust.personEddaoudi, Mohamed
display.relations<b> Is Supplemented By:</b> <br/> <ul> <li><i>[Dataset]</i> <br/> . DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc1pl3ds">10.5517/ccdc.csd.cc1pl3ds</a> HANDLE: <a href="http://hdl.handle.net/10754/663997">10754/663997</a></li></ul><b> Is Supplemented By:</b> <br/> <ul> <li><i>[Dataset]</i> <br/> . DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc1nsb0s">10.5517/ccdc.csd.cc1nsb0s</a> HANDLE: <a href="http://hdl.handle.net/10754/663998">10754/663998</a></li></ul><b> Is Supplemented By:</b> <br/> <ul> <li><i>[Dataset]</i> <br/> . DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc1ns9zq">10.5517/ccdc.csd.cc1ns9zq</a> HANDLE: <a href="http://hdl.handle.net/10754/663999">10754/663999</a></li></ul>
dc.date.published-online2018-01-11
dc.date.published-print2018-01


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