Catalytic Ester to Stannane Functional Group Interconversion via Decarbonylative Cross-Coupling of Methyl Esters

Yue, Huifeng; Zhu, Chen; Rueping, Magnus

dc.contributor.author	Yue, Huifeng
dc.contributor.author	Zhu, Chen
dc.contributor.author	Rueping, Magnus
dc.date.accessioned	2018-01-28T07:22:28Z
dc.date.available	2018-01-28T07:22:28Z
dc.date.issued	2018-01-03
dc.identifier.citation	Yue H, Zhu C, Rueping M (2018) Catalytic Ester to Stannane Functional Group Interconversion via Decarbonylative Cross-Coupling of Methyl Esters. Organic Letters 20: 385–388. Available: http://dx.doi.org/10.1021/acs.orglett.7b03669.
dc.identifier.issn	1523-7060
dc.identifier.issn	1523-7052
dc.identifier.pmid	29297229
dc.identifier.doi	10.1021/acs.orglett.7b03669
dc.identifier.uri	http://hdl.handle.net/10754/626890
dc.description.abstract	An unprecedented conversion of methyl esters to stannanes was realized, providing access to a series of arylstannanes via nickel catalysis. Various common esters including ethyl, cyclohexyl, benzyl, and phenyl esters can undergo the newly developed decarbonylative stannylation reaction. The reaction shows broad substrate scope, can differentiate between different types of esters, and if applied in consecutive fashion, allows the transformation of methyl esters into aryl fluorides or biaryls via fluororination or arylation.
dc.description.sponsorship	H.Y. was supported by the China Scholarship Council.
dc.publisher	American Chemical Society (ACS)
dc.relation.url	http://pubs.acs.org/doi/10.1021/acs.orglett.7b03669
dc.rights	This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/10.1021/acs.orglett.7b03669.
dc.title	Catalytic Ester to Stannane Functional Group Interconversion via Decarbonylative Cross-Coupling of Methyl Esters
dc.type	Article
dc.contributor.department	Chemical Science Program
dc.contributor.department	KAUST Catalysis Center (KCC)
dc.contributor.department	Physical Science and Engineering (PSE) Division
dc.identifier.journal	Organic Letters
dc.eprint.version	Post-print
dc.contributor.institution	Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany
kaust.person	Rueping, Magnus
refterms.dateFOA	2019-01-03T00:00:00Z
dc.date.published-online	2018-01-03
dc.date.published-print	2018-01-19