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    Catalytic Ester to Stannane Functional Group Interconversion via Decarbonylative Cross-Coupling of Methyl Esters

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    Type
    Article
    Authors
    Yue, Huifeng
    Zhu, Chen cc
    Rueping, Magnus cc
    KAUST Department
    Chemical Science Program
    KAUST Catalysis Center (KCC)
    Physical Science and Engineering (PSE) Division
    Date
    2018-01-03
    Online Publication Date
    2018-01-03
    Print Publication Date
    2018-01-19
    Permanent link to this record
    http://hdl.handle.net/10754/626890
    
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    Abstract
    An unprecedented conversion of methyl esters to stannanes was realized, providing access to a series of arylstannanes via nickel catalysis. Various common esters including ethyl, cyclohexyl, benzyl, and phenyl esters can undergo the newly developed decarbonylative stannylation reaction. The reaction shows broad substrate scope, can differentiate between different types of esters, and if applied in consecutive fashion, allows the transformation of methyl esters into aryl fluorides or biaryls via fluororination or arylation.
    Citation
    Yue H, Zhu C, Rueping M (2018) Catalytic Ester to Stannane Functional Group Interconversion via Decarbonylative Cross-Coupling of Methyl Esters. Organic Letters 20: 385–388. Available: http://dx.doi.org/10.1021/acs.orglett.7b03669.
    Sponsors
    H.Y. was supported by the China Scholarship Council.
    Publisher
    American Chemical Society (ACS)
    Journal
    Organic Letters
    DOI
    10.1021/acs.orglett.7b03669
    PubMed ID
    29297229
    Additional Links
    http://pubs.acs.org/doi/10.1021/acs.orglett.7b03669
    ae974a485f413a2113503eed53cd6c53
    10.1021/acs.orglett.7b03669
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

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