Catalytic Ester to Stannane Functional Group Interconversion via Decarbonylative Cross-Coupling of Methyl Esters
Type
ArticleAuthors
Yue, HuifengZhu, Chen

Rueping, Magnus

KAUST Department
Chemical Science ProgramKAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Date
2018-01-03Online Publication Date
2018-01-03Print Publication Date
2018-01-19Permanent link to this record
http://hdl.handle.net/10754/626890
Metadata
Show full item recordAbstract
An unprecedented conversion of methyl esters to stannanes was realized, providing access to a series of arylstannanes via nickel catalysis. Various common esters including ethyl, cyclohexyl, benzyl, and phenyl esters can undergo the newly developed decarbonylative stannylation reaction. The reaction shows broad substrate scope, can differentiate between different types of esters, and if applied in consecutive fashion, allows the transformation of methyl esters into aryl fluorides or biaryls via fluororination or arylation.Citation
Yue H, Zhu C, Rueping M (2018) Catalytic Ester to Stannane Functional Group Interconversion via Decarbonylative Cross-Coupling of Methyl Esters. Organic Letters 20: 385–388. Available: http://dx.doi.org/10.1021/acs.orglett.7b03669.Sponsors
H.Y. was supported by the China Scholarship Council.Publisher
American Chemical Society (ACS)Journal
Organic LettersPubMed ID
29297229Additional Links
http://pubs.acs.org/doi/10.1021/acs.orglett.7b03669ae974a485f413a2113503eed53cd6c53
10.1021/acs.orglett.7b03669
Scopus Count
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