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dc.contributor.authorLee, Shao-Chi
dc.contributor.authorLiao, Hsuan-Hung
dc.contributor.authorChatupheeraphat, Adisak
dc.contributor.authorRueping, Magnus
dc.date.accessioned2018-01-28T07:01:37Z
dc.date.available2018-01-28T07:01:37Z
dc.date.issued2018-02-15
dc.identifier.citationLee S-C, Liao H-H, Chatupheeraphat A, Rueping M (2018) Nickel-Catalyzed C-S Bond Formation via Decarbonylative Thioetherification of Esters, Amides and Intramolecular Recombination Fragment Coupling of Thioesters. Chemistry - A European Journal. Available: http://dx.doi.org/10.1002/chem.201705842.
dc.identifier.issn0947-6539
dc.identifier.doi10.1002/chem.201705842
dc.identifier.urihttp://hdl.handle.net/10754/626876
dc.description.abstractA nickel catalyzed cross-coupling protocol for the straightforward C-S bond formation has been developed. Various mercaptans and a wide range of ester and amide substrates bearing various substituents were tolerated in this process which afforded products in good to excellent yields. Furthermore, an intramolecular protocol for the synthesis of thioethers starting from thioesters has been developed. The utility of this protocol has been demonstrated in the synthesis of benzothiophene on the bench top.
dc.description.sponsorshipH.-H. Liao gratefully acknowledges the DAAD for doctoral fellowship. This research was supported by the KAUST Office of Sponsored Research under Award No. URF/1/3030-01.
dc.publisherWiley
dc.relation.urlhttp://onlinelibrary.wiley.com/doi/10.1002/chem.201705842/abstract
dc.rightsThis is the peer reviewed version of the following article: Nickel-Catalyzed C-S Bond Formation via Decarbonylative Thioetherification of Esters, Amides and Intramolecular Recombination Fragment Coupling of Thioesters, which has been published in final form at http://doi.org/10.1002/chem.201705842. This article may be used for non-commercial purposes in accordance With Wiley Terms and Conditions for self-archiving.
dc.titleNickel-Catalyzed C-S Bond Formation via Decarbonylative Thioetherification of Esters, Amides and Intramolecular Recombination Fragment Coupling of Thioesters
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalChemistry - A European Journal
dc.eprint.versionPost-print
dc.contributor.institutionRWTH Aachen; Institure of Organic Chemistry; Landoltweg 1 52074 Aachen GERMANY
kaust.personRueping, Magnus
kaust.grant.numberURF/1/3030-01
dc.date.published-online2018-02-15
dc.date.published-print2018-03-07


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