A Thieno[2,3-b]pyridine-Flanked Diketopyrrolopyrrole Polymer as an n-Type Polymer Semiconductor for All-Polymer Solar Cells and Organic Field-Effect Transistors
pTPDPP-TF Macromolecules Manuscript ID ma-2017-00934f (for publication).pdf
White, Andrew J. P.
KAUST DepartmentChemical Science Program
KAUST Solar Center (KSC)
Material Science and Engineering Program
Physical Science and Engineering (PSE) Division
Online Publication Date2017-12-28
Print Publication Date2018-01-09
Permanent link to this recordhttp://hdl.handle.net/10754/626822
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AbstractA novel fused heterocycle-flanked diketopyrrolopyrrole (DPP) monomer, thieno[2,3-b]pyridine diketopyrrolopyrrole (TPDPP), was designed and synthesized. When copolymerized with 3,4-difluorothiophene using Stille coupling polymerization, the new polymer pTPDPP-TF possesses a highly planar conjugated polymer backbone due to the fused thieno[2,3-b]pyridine flanking unit that effectively alleviates the steric hindrance with both the central DPP core and the 3,4-difluorothiophene repeat unit. This new polymer exhibits a high electron affinity (EA) of −4.1 eV and was successfully utilized as an n-type polymer semiconductor for applications in organic field-effect transistors (OFETs) and all polymer solar cells. A promising n-type charge carrier mobility of 0.1 cm2 V–1 s–1 was obtained in bottom-contact, top-gate OFETs, and a power conversion efficiency (PCE) of 2.72% with a high open-circuit voltage (VOC) of 1.04 V was achieved for all polymer solar cells using PTB7-Th as the polymer donor.
CitationChen H-Y, Nikolka M, Wadsworth A, Yue W, Onwubiko A, et al. (2017) A Thieno[2,3-b]pyridine-Flanked Diketopyrrolopyrrole Polymer as an n-Type Polymer Semiconductor for All-Polymer Solar Cells and Organic Field-Effect Transistors. Macromolecules 51: 71–79. Available: http://dx.doi.org/10.1021/acs.macromol.7b00934.
SponsorsThe authors thank KAUST for financial support and acknowledge EC FP7 Project SC2 (610115) EC H2020 (643791), and EPSRC Projects EP/G037515/1 and EP/M005143/1. Mingfei Xiao thanks the Cambridge Overseas Trust and Chinese Scholarship Council for PhD funding.
PublisherAmerican Chemical Society (ACS)
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Chen, H.-Y., Nikolka, M., Wadsworth, A., Yue, W., Onwubiko, A., Xiao, M., White, A. J. P., Baran, D., Sirringhaus, H., & McCulloch, I. (2018). CCDC 1540600: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC1NQ3S8. DOI: 10.5517/ccdc.csd.cc1nq3s8 Handle: 10754/663979