One ligand capable of in situ reaction in a mixed-ligand system with two new different frameworks

Type
Article

Authors
Wang, Xiaofang
Wang, Runwei
Liu, Xiaofang
Zhu, Pinwen
Qiu, Shilun

KAUST Grant Number
CRG-1-2012-LAI-009

Online Publication Date
2017-12-24

Print Publication Date
2017-12-17

Date
2017-12-24

Abstract
The in situ ligand 2,3-pyrazinedicarboxylic acid (2,3-H2pzdc) mixed with 1,1′-(1,4-butanediyl)bis(benzimidazole) (bbbi) is used to form two coordination polymers ([Cd(2,3-pzdc)(bbbi)] (1) and [Cd2Cl3(2-pzc)(bbbi)2] (2)) under hydrothermal conditions. Complex 1 was obtained in the absence of in situ reaction and 2 was synthesized with 2,3-H2pzdc in situ generating 2-pyrazinecarboxylate (2-pzc−). The structural details reveal that 1 has a 3D framework with dia topology, and 2 is a 2D layer structure and develops a 3D supramolecular structure via strong π⋯π stacking interactions. The ligand effects were compared for the two frameworks. In addition, fluorescence properties and thermal stabilities of 1 and 2 in the solid were studied.

Citation
Wang X, Wang R, Liu X, Zhu P, Qiu S (2017) One ligand capable of in situ reaction in a mixed-ligand system with two new different frameworks. Journal of Coordination Chemistry 70: 3971–3981. Available: http://dx.doi.org/10.1080/00958972.2017.1408914.

Acknowledgements
This work was supported by the National Natural Science Foundation of China [grant number 21390394]; the National Basic Research Program of China [grant number 2012CB821700], [grant number 2011CB808703]; NSFC [grant number 21261130584], [grant number 91022030]; “111” project (B07016); Award Project of KAUST [grant number CRG-1-2012-LAI-009]; Ministry of Education, Science and Technology Development Center Project [grant number 20120061130012]; Science and Technology Research Program of the 13th Five Year Plan, Education Department of Jilin Province.

Publisher
Informa UK Limited

Journal
Journal of Coordination Chemistry

DOI
10.1080/00958972.2017.1408914

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