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dc.contributor.authorXia, Chuan
dc.contributor.authorGuo, Jing
dc.contributor.authorLei, Yongjiu
dc.contributor.authorLiang, Hanfeng
dc.contributor.authorZhao, Chao
dc.contributor.authorAlshareef, Husam N.
dc.date.accessioned2018-01-01T12:19:04Z
dc.date.available2018-01-01T12:19:04Z
dc.date.issued2017-12-11
dc.identifier.citationXia C, Guo J, Lei Y, Liang H, Zhao C, et al. (2017) Rechargeable Aqueous Zinc-Ion Battery Based on Porous Framework Zinc Pyrovanadate Intercalation Cathode. Advanced Materials: 1705580. Available: http://dx.doi.org/10.1002/adma.201705580.
dc.identifier.issn0935-9648
dc.identifier.pmid29226488
dc.identifier.doi10.1002/adma.201705580
dc.identifier.urihttp://hdl.handle.net/10754/626636
dc.description.abstractIn this work, a microwave approach is developed to rapidly synthesize ultralong zinc pyrovanadate (Zn3V2O7(OH)2·2H2O, ZVO) nanowires with a porous crystal framework. It is shown that our synthesis strategy can easily be extended to fabricate other metal pyrovanadate compounds. The zinc pyrovanadate nanowires show significantly improved electrochemical performance when used as intercalation cathode for aqueous zinc–ion battery. Specifically, the ZVO cathode delivers high capacities of 213 and 76 mA h g−1 at current densities of 50 and 3000 mA g−1, respectively. Furthermore, the Zn//ZVO cells show good cycling stability up to 300 cycles. The estimated energy density of this Zn cell is ≈214Wh kg−1, which is much higher than commercial lead–acid batteries. Significant insight into the Zn-storage mechanism in the pyrovanadate cathodes is presented using multiple analytical methods. In addition, it is shown that our prototype device can power a 1.5 V temperature sensor for at least 24 h.
dc.description.sponsorshipC.X. and J.G. contributed equally to this work. Research reported in this publication has been supported by King Abdullah University of Science and Technology (KAUST).
dc.publisherWiley
dc.relation.urlhttp://onlinelibrary.wiley.com/doi/10.1002/adma.201705580/full
dc.subjectAqueous batteries
dc.subjectCathodes
dc.subjectPyrovanadate
dc.subjectZinc-ion batteries
dc.titleRechargeable Aqueous Zinc-Ion Battery Based on Porous Framework Zinc Pyrovanadate Intercalation Cathode
dc.typeArticle
dc.contributor.departmentComputer, Electrical and Mathematical Sciences and Engineering (CEMSE) Division
dc.contributor.departmentFunctional Nanomaterials and Devices Research Group
dc.contributor.departmentMaterial Science and Engineering Program
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalAdvanced Materials
kaust.personXia, Chuan
kaust.personGuo, Jing
kaust.personLei, Yongjiu
kaust.personLiang, Hanfeng
kaust.personZhao, Chao
kaust.personAlshareef, Husam N.
dc.date.published-online2017-12-11
dc.date.published-print2018-02


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