Nickel-Catalyzed Decarbonylative Silylation, Borylation, and Amination of Arylamides via a Deamidative Reaction Pathway
KAUST DepartmentPhysical Sciences and Engineering (PSE) Division
Chemical Science Program
KAUST Catalysis Center (KCC)
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AbstractA nickel-catalyzed decarbonylative silylation, borylation, and amination of amides has been developed. This new methodology allows the direct interconversion of amides to arylsilanes, arylboronates, and arylamines and enables a facile route for carbon–heteroatom bond formations in a straightforward and mild fashion.
CitationRueping M, Lee S-C, Guo L, Yue H, Liao H-H (2017) Nickel-Catalyzed Decarbonylative Silylation, Borylation, and Amination of Arylamides via a Deamidative Reaction Pathway. Synlett 28: 2594–2598. Available: http://dx.doi.org/10.1055/s-0036-1591495.
SponsorsL. Guo and H. Yue acknowledge the China Scholarship Council and H.-H. Liao the DAAD for a fellowship.
PublisherGeorg Thieme Verlag KG