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dc.contributor.authorTrose, Michael
dc.contributor.authorNahra, Fady
dc.contributor.authorPoater, Albert
dc.contributor.authorCordes, David B.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorCavallo, Luigi
dc.contributor.authorCazin, Catherine S. J.
dc.date.accessioned2018-01-01T12:19:03Z
dc.date.available2018-01-01T12:19:03Z
dc.date.issued2017-11
dc.identifier.citationTrose M, Nahra F, Poater A, Cordes DB, Slawin AMZ, et al. (2017) Investigating the Structure and Reactivity of Azolyl-Based Copper(I)–NHC Complexes: The Role of the Anionic Ligand. ACS Catalysis 7: 8176–8183. Available: http://dx.doi.org/10.1021/acscatal.7b02737.
dc.identifier.issn2155-5435
dc.identifier.issn2155-5435
dc.identifier.doi10.1021/acscatal.7b02737
dc.identifier.urihttp://hdl.handle.net/10754/626622
dc.description.abstractA family of copper(I)–NHC azolyl complexes was synthesized and deployed in the hydrosilylation of dicyclo-hexylketone to probe the role of the anionic ligand on catalytic performance. The azolyl ligand is shown to have a crucial role in catalytic activity without the need for additives, and this at very low catalyst loading.
dc.description.sponsorshipThe authors gratefully acknowledge the Royal Society (University Research Fellowship to C.S.J.C.), the Spanish MINECO (CTQ2014-59832-JIN), and EU (FEDER fund UNGI08-4E-003) for funding.
dc.publisherAmerican Chemical Society (ACS)
dc.relation.urlhttp://pubs.acs.org/doi/10.1021/acscatal.7b02737
dc.subjectanionic ligand
dc.subjectautocatalytic
dc.subjectcopper(I)
dc.subjectdimer
dc.subjecthydrosilylation
dc.subjectN-heterocyclic carbenes
dc.titleInvestigating the Structure and Reactivity of Azolyl-Based Copper(I)–NHC Complexes: The Role of the Anionic Ligand
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Division
dc.identifier.journalACS Catalysis
dc.contributor.institutionEaStCHEM School of Chemistry, University of St. Andrews, St. Andrews, KY16 9ST, United Kingdom
dc.contributor.institutionCentre for Sustainable Chemistry, Department of Chemistry, Ghent University, Krijgslaan 281-S3, B-9000 Ghent, Belgium
dc.contributor.institutionInstitut de Química Computacional i Catàlisi and Departament de Química, Universitat de Girona c/Maria Aurèlia Capmany 6, 17003 Girona, Spain
kaust.personPoater, Albert
kaust.personCavallo, Luigi
dc.date.published-online2017-11
dc.date.published-print2017-12


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