Coupled Interfacial Tension and Phase Behavior Model Based on Micellar Curvatures
KAUST DepartmentAli I. Al-Naimi Petroleum Engineering Research Center (ANPERC)
MetadataShow full item record
AbstractThis article introduces a consistent and robust model that predicts interfacial tensions for all microemulsion Winsor types and overall compositions. The model incorporates film bending arguments and Huh's equation and is coupled to phase behavior so that simultaneous tuning of both interfacial tension (IFT) and phase behavior is possible. The oil-water interfacial tension and characteristic length are shown to be related to each other through the hydrophilic-lipophilic deviation (HLD). The phase behavior is tied to the micelle curvatures, without the need for using the net average curvature (NAC). The interfacial tension model is related to solubilization ratios in order to introduce a coupled interfacial tension-phase behavior model for all phase environments. The approach predicts two- and three-phase interfacial tensions and phase behavior (i.e., tie lines and tie triangles) for changes in composition and HLD input parameters, such as temperature, pressure, surfactant structure, and oil equivalent alkane carbon number. Comparisons to experimental data show excellent fits and predictive capability.
CitationTorrealba VA, Johns RT (2017) Coupled Interfacial Tension and Phase Behavior Model Based on Micellar Curvatures. Langmuir 33: 13604–13614. Available: http://dx.doi.org/10.1021/acs.langmuir.7b03372.
SponsorsThe authors thank the member companies of the Enhanced Oil Recovery JIP in the EMS Energy Institute at The Pennsylvania State University at University Park, PA for their financial support. R.T.J. is Chair of the undergraduate Petroleum and Natural Gas Engineering program and holds the Victor and Anna Mae Beghini Faculty Fellowship in Petroleum and Natural Gas Engineering at The Pennsylvania State University. He also holds the Energi Simulation Chair in Fluid Behavior and Rock Interactions at Penn State.
PublisherAmerican Chemical Society (ACS)
- Dimensionless Equation of State to Predict Microemulsion Phase Behavior.
- Authors: Ghosh S, Johns RT
- Issue date: 2016 Sep 6
- Hydrophilic-lipophilic deviation (HLD) method for characterizing conventional and extended surfactants.
- Authors: Witthayapanyanon A, Harwell JH, Sabatini DA
- Issue date: 2008 Sep 1
- Van der Waals free energy model for solubilization of oil in micelles.
- Authors: Troncoso AB, Acosta E
- Issue date: 2015 Jan 21
- Predicting solubilisation features of ternary phase diagrams of fully dilutable lecithin linker microemulsions.
- Authors: Nouraei M, Acosta EJ
- Issue date: 2017 Jun 1
- On the instability of emulsions made with surfactant-oil-water systems at optimum formulation with ultralow interfacial tensions.
- Authors: Marquez R, Forgiarini A, Langevin D, Salager JL
- Issue date: 2018 Jul 9