Water promoted allylic nucleophilic substitution reactions of (E)-1,3 diphenylallyl acetate

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Type
Article
Authors
Ghorpade, Seema Arun
Sawant, Dinesh
Makki, Arwa cc
Sekar, N
Eppinger, Jörg cc
KAUST Department
Biological & Organometallic Catalysis Laboratories
Biological and Environmental Sciences and Engineering (BESE) Division
Chemical Engineering Program
Chemical Science Program
KAUST Catalysis Center (KCC)
Office of the VP
Physical Science and Engineering (PSE) Division
Young Talent Development
KAUST Grant Number
FIC/2010/07
Date
2018
Permanent link to this record
http://hdl.handle.net/10754/626330

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Abstract
Transition metal free, water based, greener protocol for allylic alkylation, allylic amination, O-allylation of (E)-1,3-diphenylallyl acetate is described. The developed methodology is applicable for a wide range of nucleophiles furnishing excellent yields of corresponding products up to 87% under mild reaction conditions. A Distinct effect of water and base is explored for allylic nucleophilic substitution reactions of (E)-1,3-diphenylallyl acetate.
Citation
Ghorpade SA, Sawant DN, Makki A, Sekar N, Eppinger J (2017) Water promoted allylic nucleophilic substitution reactions of (E)-1,3 diphenylallyl acetate. Green Chemistry. Available: http://dx.doi.org/10.1039/c7gc03123h.
Sponsors
The author Seema Arun Ghorpade is thankful to the Department of Science and Technology (DST) India for providing DST INSPIRE Senior Research Fellowship and Institute of Chemical Technology, Matunga, Mumbai. This work was supported by the King Abdullah University of Science and Technology (KAUST baseline funding and GCR grant FIC/2010/07). All authors are gratefully acknowledging support from King Abdullah University of Science and Technology (KAUST), Saudi Arabia.
Publisher
Royal Society of Chemistry (RSC)
Journal
Green Chemistry
DOI
10.1039/c7gc03123h
Additional Links
http://pubs.rsc.org/en/Content/ArticleLanding/2017/GC/C7GC03123H#!divAbstract
Collections
Articles; Biological and Environmental Science and Engineering (BESE) Division; Physical Science and Engineering (PSE) Division; Chemical Science Program; Chemical Engineering Program; KAUST Catalysis Center (KCC)