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dc.contributor.authorSun, Xiaohui
dc.contributor.authorSuarez, Alma I. Olivos
dc.contributor.authorMeijerink, Mark
dc.contributor.authorvan Deelen, Tom
dc.contributor.authorOuld-Chikh, Samy
dc.contributor.authorZečević, Jovana
dc.contributor.authorde Jong, Krijn P.
dc.contributor.authorKapteijn, Freek
dc.contributor.authorGascon, Jorge
dc.date.accessioned2017-11-29T11:13:56Z
dc.date.available2017-11-29T11:13:56Z
dc.date.issued2017-11-22
dc.identifier.citationSun X, Suarez AIO, Meijerink M, van Deelen T, Ould-Chikh S, et al. (2017) Manufacture of highly loaded silica-supported cobalt Fischer–Tropsch catalysts from a metal organic framework. Nature Communications 8. Available: http://dx.doi.org/10.1038/s41467-017-01910-9.
dc.identifier.issn2041-1723
dc.identifier.pmid29162823
dc.identifier.doi10.1038/s41467-017-01910-9
dc.identifier.urihttp://hdl.handle.net/10754/626237
dc.description.abstractThe development of synthetic protocols for the preparation of highly loaded metal nanoparticle-supported catalysts has received a great deal of attention over the last few decades. Independently controlling metal loading, nanoparticle size, distribution, and accessibility has proven challenging because of the clear interdependence between these crucial performance parameters. Here we present a stepwise methodology that, making use of a cobalt-containing metal organic framework as hard template (ZIF-67), allows addressing this long-standing challenge. Condensation of silica in the Co-metal organic framework pore space followed by pyrolysis and subsequent calcination of these composites renders highly loaded cobalt nanocomposites (~ 50 wt.% Co), with cobalt oxide reducibility in the order of 80% and a good particle dispersion, that exhibit high activity, C5 + selectivity and stability in Fischer-Tropsch synthesis.
dc.description.sponsorshipWe thank C. Hernandez-Mejia for additional FTS testing, H. Oosterbeek for the GC analysis and A. Dikhtiarenko for help in the design of the graphical abstract. X.S. acknowledges financial support from China Scholarship Council (CSC).
dc.publisherSpringer Nature
dc.relation.urlhttps://www.nature.com/articles/s41467-017-01910-9
dc.rightsThis article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.titleManufacture of highly loaded silica-supported cobalt Fischer–Tropsch catalysts from a metal organic framework
dc.typeArticle
dc.contributor.departmentChemical Engineering Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalNature Communications
dc.eprint.versionPublisher's Version/PDF
dc.contributor.institutionCatalysis Engineering, Chemical Engineering Department, Delft University of Technology, Van der Maasweg 9, 2629, HZ, Delft, The Netherlands.
dc.contributor.institutionInorganic Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Utrecht University, Universiteitsweg 99, 3584, CG, Utrecht, The Netherlands.
kaust.personOuld-Chikh, Samy
kaust.personGascon, Jorge
refterms.dateFOA2018-06-13T19:04:52Z
dc.date.published-online2017-11-22
dc.date.published-print2017-12


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This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
Except where otherwise noted, this item's license is described as This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.