Facial One-Pot Synthesis of D 3h Symmetric Bicyclocalixarenetriazines and Their Layered Comb Self-Assembly
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AbstractA number of D3h symmetric bicyclocalixarenetriazine core compounds were synthesized via a general and good-yielding (43-48% yield) facile protocol starting from cyanuric halides, phloroglucinol and K2CO3 under very mild reaction conditions. These cage-like compounds are tolerate with different reaction conditions and can be derived with other functional groups in high yield. The X-ray crystal structures show these compounds have slightly distorted D3h symmetric structures. Due to the unique molecular topological structure, bicyclocalixarenetriazine molecules form unique layered comb networks when hydrogen bond groups exist (such as CO2H, B(OH)2), which represent a new kind of building block unit for supramolecular architectures.
CitationChen Y, Jiahui W, Xu H, Qianqian L, Jing J (2017) Facial one-pot synthesis of D 3h symmetric bicyclocalixarenetriazines and their layered comb self-assembly. Journal of Saudi Chemical Society. Available: http://dx.doi.org/10.1016/j.jscs.2017.11.003.
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