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    A Fine-Tuned MOF for Gas and Vapor Separation: A Multipurpose Adsorbent for Acid Gas Removal, Dehydration, and BTX Sieving

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    Type
    Article
    Authors
    Haja Mohideen, Mohamed Infas
    Pillai, Renjith S. cc
    Adil, Karim cc
    Bhatt, Prashant
    Belmabkhout, Youssef cc
    Shkurenko, Aleksander cc
    Maurin, Guillaume cc
    Eddaoudi, Mohamed cc
    KAUST Department
    Advanced Membranes and Porous Materials Research Center
    Chemical Science Program
    Functional Materials Design, Discovery and Development (FMD3)
    Physical Science and Engineering (PSE) Division
    Date
    2017-10-19
    Online Publication Date
    2017-10-19
    Print Publication Date
    2017-11
    Permanent link to this record
    http://hdl.handle.net/10754/626051
    
    Metadata
    Show full item record
    Abstract
    Summary The development of highly stable separation agents is recognized as a decisive step toward the successful deployment of energy-efficient and cost-effective separation processes. Here, we report the synthesis and construction of a metal-organic framework (MOF), kag-MOF-1, that has adequate structural and chemical features and affords a stable adsorbent with unique and appropriate adsorption properties for gas processing akin to acid gas removal, dehydration, and benzene-toluene-xylene (BTX) sieving. A combination of X-ray diffraction experiments, adsorption studies, mixed-gas breakthrough adsorption column testing, calorimetric measurements, and molecular simulations corroborated the exceptional separation performance of kag-MOF-1 and its prospective use as a multifunctional adsorbent. The unique adsorption properties of kag-MOF-1, resulting from the contracted pore system with aligned periodic array of exposed functionalities, attest to the prominence of this new generation of ultra-microporous material as a prospective practical adsorbent toward cost-effective and more simplified gas and vapor processing flowcharts for natural gas upgrading and flue gas scrubbing.
    Citation
    Mohideen MIH, Pillai RS, Adil K, Bhatt PM, Belmabkhout Y, et al. (2017) A Fine-Tuned MOF for Gas and Vapor Separation: A Multipurpose Adsorbent for Acid Gas Removal, Dehydration, and BTX Sieving. Chem. Available: http://dx.doi.org/10.1016/j.chempr.2017.09.002.
    Sponsors
    King Abdullah University of Science and Technology
    Publisher
    Elsevier BV
    Journal
    Chem
    DOI
    10.1016/j.chempr.2017.09.002
    Additional Links
    http://www.sciencedirect.com/science/article/pii/S2451929417303674
    Relations
    Is Supplemented By:
    • [Dataset]
      Mohideen, M. I. H., Pillai, R. S., Adil, K., Bhatt, P. M., Belmabkhout, Y., Shkurenko, A., Maurin, G., & Eddaoudi, M. (2017). CCDC 1491855: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC1M2DCG. DOI: 10.5517/ccdc.csd.cc1m2dcg Handle: 10754/663917
    ae974a485f413a2113503eed53cd6c53
    10.1016/j.chempr.2017.09.002
    Scopus Count
    Collections
    Articles; Advanced Membranes and Porous Materials Research Center; Physical Science and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program

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