A Fine-Tuned MOF for Gas and Vapor Separation: A Multipurpose Adsorbent for Acid Gas Removal, Dehydration, and BTX Sieving
AuthorsHaja Mohideen, Mohamed Infas
Pillai, Renjith S.
KAUST DepartmentAdvanced Membranes and Porous Materials Research Center
Chemical Science Program
Functional Materials Design, Discovery and Development (FMD3)
Physical Science and Engineering (PSE) Division
Online Publication Date2017-10-19
Print Publication Date2017-11
Permanent link to this recordhttp://hdl.handle.net/10754/626051
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AbstractSummary The development of highly stable separation agents is recognized as a decisive step toward the successful deployment of energy-efficient and cost-effective separation processes. Here, we report the synthesis and construction of a metal-organic framework (MOF), kag-MOF-1, that has adequate structural and chemical features and affords a stable adsorbent with unique and appropriate adsorption properties for gas processing akin to acid gas removal, dehydration, and benzene-toluene-xylene (BTX) sieving. A combination of X-ray diffraction experiments, adsorption studies, mixed-gas breakthrough adsorption column testing, calorimetric measurements, and molecular simulations corroborated the exceptional separation performance of kag-MOF-1 and its prospective use as a multifunctional adsorbent. The unique adsorption properties of kag-MOF-1, resulting from the contracted pore system with aligned periodic array of exposed functionalities, attest to the prominence of this new generation of ultra-microporous material as a prospective practical adsorbent toward cost-effective and more simplified gas and vapor processing flowcharts for natural gas upgrading and flue gas scrubbing.
CitationMohideen MIH, Pillai RS, Adil K, Bhatt PM, Belmabkhout Y, et al. (2017) A Fine-Tuned MOF for Gas and Vapor Separation: A Multipurpose Adsorbent for Acid Gas Removal, Dehydration, and BTX Sieving. Chem. Available: http://dx.doi.org/10.1016/j.chempr.2017.09.002.
SponsorsKing Abdullah University of Science and Technology
RelationsIs Supplemented By:
Mohideen, M. I. H., Pillai, R. S., Adil, K., Bhatt, P. M., Belmabkhout, Y., Shkurenko, A., Maurin, G., & Eddaoudi, M. (2017). CCDC 1491855: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC1M2DCG. DOI: 10.5517/ccdc.csd.cc1m2dcg Handle: 10754/663917