Extending the Second-Generation Phosphorus-Nitrogen PN3 -Pincer Ligand Family through Ligand Post-Modification
KAUST DepartmentChemical Science Program
KAUST Catalysis Center (KCC)
Physical Sciences and Engineering (PSE) Division
KAUST Grant NumberURF/1/3018–01-01
Permanent link to this recordhttp://hdl.handle.net/10754/626027
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AbstractA series of air-stable nickel complexes containing triazine-based PN3P-pincer ligands were synthesized and fully characterized. Complex 3 contains a de-aromatized central triazine ring from the deprotonation of one of the N–H arms. With a post-modification strategy, the Me-PN3P*NiCl complex (3) could be converted into a new class of diimine–traizine PN3P-pincer nickel complexes.
CitationHuang M-H, Hu J, Huang K-W (2017) Extending the Second-Generation Phosphorus-Nitrogen PN3 -Pincer Ligand Family through Ligand Post-Modification. Journal of the Chinese Chemical Society. Available: http://dx.doi.org/10.1002/jccs.201700205.
SponsorsFinancial support for this work was provided by the King Abdullah University of Science and Technology (URF/1/3018–01-01).