Extending the Second-Generation Phosphorus-Nitrogen PN3 -Pincer Ligand Family through Ligand Post-Modification

Type
Article
Authors
Huang, Mei-Hui
Hu, Jinsong
Huang, Kuo-Wei cc
KAUST Department
Chemical Science Program
Homogeneous Catalysis Laboratory (HCL)
KAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
KAUST Grant Number
URF/1/3018–01-01
Date
2017-10-02
Online Publication Date
2017-10-02
Print Publication Date
2018-01
Permanent link to this record
http://hdl.handle.net/10754/626027

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Abstract
A series of air-stable nickel complexes containing triazine-based PN3P-pincer ligands were synthesized and fully characterized. Complex 3 contains a de-aromatized central triazine ring from the deprotonation of one of the N–H arms. With a post-modification strategy, the Me-PN3P*NiCl complex (3) could be converted into a new class of diimine–traizine PN3P-pincer nickel complexes.
Citation
Huang M-H, Hu J, Huang K-W (2017) Extending the Second-Generation Phosphorus-Nitrogen PN3 -Pincer Ligand Family through Ligand Post-Modification. Journal of the Chinese Chemical Society. Available: http://dx.doi.org/10.1002/jccs.201700205.
Sponsors
Financial support for this work was provided by the King Abdullah University of Science and Technology (URF/1/3018–01-01).
Publisher
Wiley
Journal
Journal of the Chinese Chemical Society
DOI
10.1002/jccs.201700205
Additional Links
http://onlinelibrary.wiley.com/doi/10.1002/jccs.201700205/full
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Collections
Articles; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)