KAUST DepartmentPhysical Sciences and Engineering (PSE) Division
Computer, Electrical and Mathematical Sciences and Engineering (CEMSE) Division
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AbstractThe first successful fabrication of microsupercapacitors (μ-SCs) using fractal electrode designs is reported. Using sputtered anhydrous RuO thin-film electrodes as prototypes, μ-SCs are fabricated using Hilbert, Peano, and Moore fractal designs, and their performance is compared to conventional interdigital electrode structures. Microsupercapacitor performance, including energy density, areal and volumetric capacitances, changes with fractal electrode geometry. Specifically, the μ-SCs based on the Moore design show a 32% enhancement in energy density compared to conventional interdigital structures, when compared at the same power density and using the same thin-film RuO electrodes. The energy density of the Moore design is 23.2 mWh cm at a volumetric power density of 769 mW cm. In contrast, the interdigital design shows an energy density of only 17.5 mWh cm at the same power density. We show that active electrode surface area cannot alone explain the increase in capacitance and energy density. We propose that the increase in electrical lines of force, due to edging effects in the fractal electrodes, also contribute to the higher capacitance. This study shows that electrode fractal design is a viable strategy for improving the performance of integrated μ-SCs that use thin-film electrodes at no extra processing or fabrication cost.
CitationHota MK, Jiang Q, Mashraei Y, Salama KN, Alshareef HN (2017) Fractal Electrochemical Microsupercapacitors. Advanced Electronic Materials 3: 1700185. Available: http://dx.doi.org/10.1002/aelm.201700185.
SponsorsResearch reported in this publication was supported by King Abdullah University of Science and Technology (KAUST). The authors thank the nanofabrication laboratory staff and the imaging and characterization laboratory staff at KAUST, especially Elhadj M. Diallo for their excellent support.
JournalAdvanced Electronic Materials