One-Pot Synthesis of Size- and Composition-Controlled Ni-Rich NiPt Alloy Nanoparticles in a Reverse Microemulsion System and Their Application
Anjum, Dalaver H.
KAUST DepartmentAnalytical Chemistry Core Lab
Chemical Science Program
Imaging & Characterization Core Lab, King Abdullah University of Science and Technology, Thuwal 23955-6900, Saudi Arabia
Imaging and Characterization Core Lab
KAUST Catalysis Center, King Abdullah University of Science and Technology, Thuwal 23955-6900, Saudi Arabia
KAUST Catalysis Center (KCC)
Material Science and Engineering Program
Nanofabrication Core Lab
Physical Science and Engineering (PSE) Division
Online Publication Date2017-08-29
Print Publication Date2017-09-13
Permanent link to this recordhttp://hdl.handle.net/10754/625994
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AbstractBimetallic nanoparticles have been the subject of numerous research studies in the nanotechnology field, in particular for catalytic applications. Control of the size, morphology, and composition has become a key challenge due to the relationship between these parameters and the catalytic behavior of the particles in terms of activity, selectivity, and stability. Here, we present a one-pot air synthesis of 2 nm NiPt nanoparticles with a narrow size distribution. Control of the size and composition of the alloy particles is achieved at ambient temperature, in the aqueous phase, by the simultaneous reduction of nickel and platinum precursors with hydrazine, using a reverse microemulsion system. After deposition on an alumina support, this Ni-rich nanoalloy exhibits unprecedented stability under the harsh conditions of methane dry reforming.
CitationBiausque GM, Laveille PV, Anjum DH, Zhang B, Zhang X, et al. (2017) One-Pot Synthesis of Size- and Composition-Controlled Ni-Rich NiPt Alloy Nanoparticles in a Reverse Microemulsion System and Their Application. ACS Applied Materials & Interfaces 9: 30643–30653. Available: http://dx.doi.org/10.1021/acsami.7b08201.
SponsorsWe thank Saudi Basic Industries Corp. (SABIC) for its financial support and scientific contribution as well as KAUST for their exceptional facilities.
PublisherAmerican Chemical Society (ACS)