Functionalized Nanochannels from Self-Assembled and Photomodified Poly(Styrene-b -Butadiene-b -Styrene)
Nunes, Suzana Pereira
KAUST DepartmentAdvanced Membranes and Porous Materials Research Center
Biological and Environmental Sciences and Engineering (BESE) Division
Chemical Engineering Program
Chemical Science Program
Environmental Science and Engineering Program
Imaging and Characterization Core Lab
KAUST Catalysis Center (KCC)
Nanofabrication Core Lab
Nanostructured Polymeric Membrane Lab
Physical Science and Engineering (PSE) Division
Polymer Synthesis Laboratory
Water Desalination and Reuse Research Center (WDRC)
KAUST Grant Number1671 – CRG2
Online Publication Date2017-10-04
Print Publication Date2018-05
Permanent link to this recordhttp://hdl.handle.net/10754/625830
MetadataShow full item record
AbstractMembranes are prepared by self-assembly and casting of 5 and 13 wt% poly(styrene-b-butadiene-b-styrene) (PS-b-PB-b-PS) copolymers solutions in different solvents, followed by immersion in water or ethanol. By controlling the solution-casting gap, porous films of 50 and 1 µm thickness are obtained. A gradient of increasing pore size is generated as the distance from the surface increased. An ordered porous surface layer with continuous nanochannels can be observed. Its formation is investigated, by using time-resolved grazing incident small angle X-ray scattering, electron microscopy, and rheology, suggesting a strong effect of the air-solution interface on the morphology formation. The thin PS-b-PB-b-PS ordered films are modified, by promoting the photolytic addition of thioglycolic acid to the polybutadiene groups, adding chemical functionality and specific transport characteristics on the preformed nanochannels, without sacrificing the membrane morphology. Photomodification increases fivefold the water permeance to around 2 L m(-2) h(-1) bar(-1) , compared to that of the unmodified one. A rejection of 74% is measured for methyl orange in water. The membranes fabrication with tailored nanochannels and chemical functionalities can be demonstrated using relatively lower cost block copolymers. Casting on porous polyacrylonitrile supports makes the membranes even more scalable and competitive in large scale.
CitationSutisna B, Polymeropoulos G, Musteata V, Sougrat R, Smilgies D-M, et al. (2017) Functionalized Nanochannels from Self-Assembled and Photomodified Poly(Styrene-b -Butadiene-b -Styrene). Small: 1701885. Available: http://dx.doi.org/10.1002/smll.201701885.
SponsorsThis work was sponsored by the King Abdullah University of Science and Technology (KAUST) Grant 1671 – CRG2. The authors thank Christopher Waldron, Nimer Wehbe, and Mohamed Nejib Hedhili for the assistance on the XPS measurements, as well as Alessandro Genovese for the EFTEM and STEM–EELS analysis, and Long Chen for the assistance in the AFM measurements. The authors acknowledge Cornell High Energy Synchrotron Source (CHESS) in USA and Laboratório Nacional de Luz Síncrotron (LNLS) in Brazil for the access to the GISAXS and SAXS synchrotron facilities. The authors thank Florian Meneau and Tiago Araujo Kakile at LNLS for their support at the SAXS1 beamline. CHESS was supported by the National Science Foundation and the National Institutes of Health/National Institute of General Medical Sciences under NSF award DMR-1332208.
CollectionsNanofabrication Core Lab; Nanofabrication Core Lab; Articles; Biological and Environmental Sciences and Engineering (BESE) Division; Advanced Membranes and Porous Materials Research Center; Environmental Science and Engineering Program; Environmental Science and Engineering Program; Imaging and Characterization Core Lab; Imaging and Characterization Core Lab; Physical Science and Engineering (PSE) Division; Physical Science and Engineering (PSE) Division; Chemical Science Program; Chemical Science Program; Chemical Engineering Program; Chemical Engineering Program; KAUST Catalysis Center (KCC); KAUST Catalysis Center (KCC); Water Desalination and Reuse Research Center (WDRC); Water Desalination and Reuse Research Center (WDRC)
- Carboxyl-functionalized nanochannels based on block copolymer hierarchical structures.
- Authors: Musteata VE, Chisca S, Meneau F, Smilgies DM, Nunes SP
- Issue date: 2018 Sep 28
- Exploring the Self-Assembly Capabilities of ABA-Type SBS, SIS, and Their Analogous Hydrogenated Copolymers onto Different Nanostructures Using Atomic Force Microscopy.
- Authors: Politakos N, Kortaberria G
- Issue date: 2018 Aug 24
- Control of the orientation of symmetric poly(styrene)-block-poly(D,L-lactide) block copolymers using statistical copolymers of dissimilar composition.
- Authors: Keen I, Yu A, Cheng HH, Jack KS, Nicholson TM, Whittaker AK, Blakey I
- Issue date: 2012 Nov 13
- Volume shrinkage and rheological studies of epoxidised and unepoxidised poly(styrene-block-butadiene-block-styrene) triblock copolymer modified epoxy resin-diamino diphenyl methane nanostructured blend systems.
- Authors: George SM, Puglia D, Kenny JM, Parameswaranpillai J, Vijayan P P, Pionteck J, Thomas S
- Issue date: 2015 May 21
- Solvothermal Vapor Annealing of Lamellar Poly(styrene)-block-poly(d,l-lactide) Block Copolymer Thin Films for Directed Self-Assembly Application.
- Authors: Cummins C, Mokarian-Tabari P, Andreazza P, Sinturel C, Morris MA
- Issue date: 2016 Mar