Fabrication of Polybenzimidazole/Palladium Nanoparticles Hollow Fiber Membranes for Hydrogen Purification
KAUST DepartmentAdvanced Membranes and Porous Materials Research Center
Chemical Engineering Program
Physical Science and Engineering (PSE) Division
Water Desalination and Reuse Research Center (WDRC)
Online Publication Date2017-09-13
Print Publication Date2018-01
Permanent link to this recordhttp://hdl.handle.net/10754/625768
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AbstractA novel scheme to fabricate polybenzimidazole (PBI) hollow fiber membranes with a thin skin loaded with fully dispersed palladium nanoparticles is proposed for the first time. Palladium is added to the membrane during the spinning process in the form of ions that coordinate to the imidazole groups of the polymer. This is attractive for membrane production because agglomeration of nanoparticles is minimized and the high-cost metal is incorporated in only the selective layer—where it is required. Pd-containing membranes achieve three orders of magnitude higher H2 permeances and a twofold improvement in H2/CO2 selectivity compared to pure PBI hollow fiber membranes.
CitationVillalobos LF, Hilke R, Akhtar FH, Peinemann K-V (2017) Fabrication of Polybenzimidazole/Palladium Nanoparticles Hollow Fiber Membranes for Hydrogen Purification. Advanced Energy Materials: 1701567. Available: http://dx.doi.org/10.1002/aenm.201701567.
SponsorsThis research was supported by King Abdullah University of Science and Technology (KAUST).
JournalAdvanced Energy Materials