Polynuclear Iron-Oxo/Hydroxy Complexes of Ketoacidoximate Ligands: Synthesis, Structures and Conversion to Ferric Oxide
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ArticleDate
2017-06-13Online Publication Date
2017-06-13Print Publication Date
2017-06-12Permanent link to this record
http://hdl.handle.net/10754/625610
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The polynuclear iron-oxo/hydroxy complexes containing ketoacidoximate ligands described in this report are [Fe3(μ3-O){O2C-C(C6H5)=NOCH3}6(py)3] (1) (py=pyridine), [Fe2(μ3-O){O2C-C(CH2-C6H5)=NO}2(H2O)(CH3OH)]2 (2) and [{Fe(μ2-OH)(O2C-C(CH3)=NO)}(dmso)]6 (3) (dmso=dimethyl sulfoxide). 1–3 are isolated from the reaction of Fe(NO3)3⋅9H2O and in situ generated anions of ketoacidoximate ligand [(HO2C-C(R1)=NOR2), where R1=CH3, C6H5 and CH2-C6H5; R2=H or CH3] in H2O, followed by crystallization in donor solvents. 1–3 undergo thermal decomposition above 200 °C and form crystalline α-Fe2O3 at 600 °C.Citation
Davaasuren B, Khanderi J, Rothenberger A (2017) Polynuclear Iron-Oxo/Hydroxy Complexes of Ketoacidoximate Ligands: Synthesis, Structures and Conversion to Ferric Oxide. ChemistrySelect 2: 4642–4647. Available: http://dx.doi.org/10.1002/slct.201701034.Sponsors
This work was supported by the King Abdullah University of Science and Technology (KAUST) baseline and AEA funding.Publisher
WileyJournal
ChemistrySelectAdditional Links
http://onlinelibrary.wiley.com/doi/10.1002/slct.201701034/abstractRelations
Is Supplemented By:- [Dataset]
. DOI: 10.5517/ccdc.csd.cc1lnl61 HANDLE: 10754/663822
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. DOI: 10.5517/ccdc.csd.cc1lnl72 HANDLE: 10754/663823
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. DOI: 10.5517/ccdc.csd.cc1lnl50 HANDLE: 10754/663824
ae974a485f413a2113503eed53cd6c53
10.1002/slct.201701034