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dc.contributor.authorAssi, Hala
dc.contributor.authorMouchaham, Georges
dc.contributor.authorSteunou, Nathalie
dc.contributor.authorDevic, Thomas
dc.contributor.authorSerre, Christian
dc.date.accessioned2017-06-21T06:48:05Z
dc.date.available2017-06-21T06:48:05Z
dc.date.issued2017
dc.identifier.citationAssi H, Mouchaham G, Steunou N, Devic T, Serre C (2017) Titanium coordination compounds: from discrete metal complexes to metal–organic frameworks. Chem Soc Rev 46: 3431–3452. Available: http://dx.doi.org/10.1039/c7cs00001d.
dc.identifier.issn0306-0012
dc.identifier.issn1460-4744
dc.identifier.doi10.1039/c7cs00001d
dc.identifier.urihttp://hdl.handle.net/10754/625114
dc.description.abstractOwing to their promise in photocatalysis and optoelectronics, titanium based metal–organic frameworks (MOFs) are one of the most appealing classes of MOFs reported to date. Nevertheless, Ti-MOFs are still very scarce because of their challenging synthesis associated with a poor degree of control of their chemistry and crystallization. This review aims at giving an overview of the recent progress in this field focusing on the most relevant existing titanium coordination compounds as well as their promising photoredox properties. Not only Ti-MOFs but also Ti-oxo-clusters will be discussed and particular interest will be dedicated to highlight the different successful synthetic strategies allowing to overcome the still “unpredictable” reactivity of titanium ions, particularly to afford crystalline porous coordination polymers.
dc.description.sponsorshipThe authors acknowledge past and present coworkers involved in the synthesis and characterization of new MOFs, especially those involved in the chemistry of Ti-MOFs (H. Dan-Hardi, V. Guillerm, N. Guillou, P. Horcajada, T. L. A. Nguyen, F. Nouar, L. C. Pardo-Perez, F. Ragon and G. Férey).
dc.publisherRoyal Society of Chemistry (RSC)
dc.relation.urlhttp://pubs.rsc.org/en/Content/ArticleLanding/2017/CS/C7CS00001D#!divAbstract
dc.titleTitanium coordination compounds: from discrete metal complexes to metal–organic frameworks
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalChem. Soc. Rev.
dc.contributor.institutionInstitut Lavoisier, UMR CNRS 8180, Université de Versailles St-Quentin en Yvelines, Université Paris Saclay, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France
dc.contributor.institutionInstitut des Matériaux Jean Rouxel (IMN), UMR 6502, Université de Nantes, CNRS, 2 rue de la Houssinière, BP 32229, 44322 Nantes Cedex 3, France
dc.contributor.institutionInstitut des Matériaux Poreux de Paris, FRE 2000 CNRS Ecole Normale Supérieure, Ecole Supérieure de Physique et de Chimie Industrielles de Paris, PSL Research University, 75005 Paris, France
kaust.personMouchaham, Georges


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