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dc.contributor.authorLiu, Xiangqian
dc.contributor.authorJia, Jiaqi
dc.contributor.authorRueping, Magnus
dc.date.accessioned2017-06-21T06:48:05Z
dc.date.available2017-06-21T06:48:05Z
dc.date.issued2017-06-07
dc.identifier.citationLiu X, Jia J, Rueping M (2017) Nickel-Catalyzed C–O Bond-Cleaving Alkylation of Esters: Direct Replacement of the Ester Moiety by Functionalized Alkyl Chains. ACS Catalysis 7: 4491–4496. Available: http://dx.doi.org/10.1021/acscatal.7b00941.
dc.identifier.issn2155-5435
dc.identifier.issn2155-5435
dc.identifier.doi10.1021/acscatal.7b00941
dc.identifier.urihttp://hdl.handle.net/10754/625106
dc.description.abstractTwo efficient protocols for the nickel-catalyzed aryl–alkyl cross-coupling reactions using esters as coupling components have been established. The methods enable the selective oxidative addition of nickel to acyl C–O and aryl C–O bonds and allow the aryl–alkyl cross-coupling via decarbonylative bond cleavage or through cleavage of a C–O bond with high efficiency and good functional group compatibility. The protocols allow the streamlined, unconventional utilization of widespread ester groups and their precursors, carboxylic acids and phenols, in synthetic organic chemistry.
dc.description.sponsorshipX.L. was supported by the China Scholarship Council.
dc.publisherAmerican Chemical Society (ACS)
dc.relation.urlhttp://pubs.acs.org/doi/full/10.1021/acscatal.7b00941
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/full/10.1021/acscatal.7b00941.
dc.subjectalkylation
dc.subjectcross-coupling
dc.subjectC−O activation
dc.subjectdecarbonylation
dc.subjectnickel catalysis
dc.titleNickel-Catalyzed C–O Bond-Cleaving Alkylation of Esters: Direct Replacement of the Ester Moiety by Functionalized Alkyl Chains
dc.typeArticle
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Division
dc.contributor.departmentChemical Science Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.identifier.journalACS Catalysis
dc.eprint.versionPost-print
dc.contributor.institutionInstitute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany
kaust.personRueping, Magnus
refterms.dateFOA2018-06-07T00:00:00Z


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