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    Amide to Alkyne Interconversion via a Nickel/Copper-Catalyzed Deamidative Cross-Coupling of Aryl and Alkenyl Amides

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    Type
    Article
    Authors
    Srimontree, Watchara
    Chatupheeraphat, Adisak
    Liao, Hsuan-Hung
    Rueping, Magnus cc
    KAUST Department
    Chemical Science Program
    KAUST Catalysis Center (KCC)
    Physical Science and Engineering (PSE) Division
    Date
    2017-06-05
    Permanent link to this record
    http://hdl.handle.net/10754/625096
    
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    Abstract
    A nickel-catalyzed deamidative cross-coupling reaction of amides with terminal alkynes as coupling partners was disclosed. This newly developed methodology allows the direct interconversion of amides to alkynes and enables a facile route for C(sp2)-C(sp) bond formation in a straightforward and mild fashion.
    Citation
    Srimontree W, Chatupheeraphat A, Liao H-H, Rueping M (2017) Amide to Alkyne Interconversion via a Nickel/Copper-Catalyzed Deamidative Cross-Coupling of Aryl and Alkenyl Amides. Organic Letters 19: 3091–3094. Available: http://dx.doi.org/10.1021/acs.orglett.7b01194.
    Sponsors
    H.-H.L. acknowledges the DAAD for a doctoral fellowship.
    Publisher
    American Chemical Society (ACS)
    Journal
    Organic Letters
    DOI
    10.1021/acs.orglett.7b01194
    PubMed ID
    28581761
    Additional Links
    http://pubs.acs.org/doi/full/10.1021/acs.orglett.7b01194
    ae974a485f413a2113503eed53cd6c53
    10.1021/acs.orglett.7b01194
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

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