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dc.contributor.authorFei, Zhuping
dc.contributor.authorChen, Lei
dc.contributor.authorHan, Yang
dc.contributor.authorGann, Eliot
dc.contributor.authorChesman, Anthony
dc.contributor.authorMcNeill, Christopher R.
dc.contributor.authorAnthopoulos, Thomas D.
dc.contributor.authorHeeney, Martin
dc.contributor.authorPietrangelo, Agostino
dc.date.accessioned2017-06-12T08:33:41Z
dc.date.available2017-06-12T08:33:41Z
dc.date.issued2017-06-12
dc.identifier.citationFei Z, Chen L, Han Y, Gann E, Chesman A, et al. (2017) An Alternating 5,5-Dimethylcyclopentadiene-based Copolymer prepared at Room Temperature for High Performance Organic Thin Film Transistors. Journal of the American Chemical Society. Available: http://dx.doi.org/10.1021/jacs.7b03279.
dc.identifier.issn0002-7863
dc.identifier.issn1520-5126
dc.identifier.pmid28578574
dc.identifier.doi10.1021/jacs.7b03279
dc.identifier.urihttp://hdl.handle.net/10754/624897
dc.description.abstractWe report that the inclusion of non-aromatic 5,5-dimethylcyclopentadiene monomer into a conjugated backbone is an attractive strategy to high performance semiconducting polymers. The use of this monomer enables a room temperature Suzuki copolymerization with a diketopyrrolopyrrole comono-mer to afford a highly soluble, high molecular weight material. The resulting low band gap polymer exhibits excellent photo and thermal stability, and despite a large π-π stacking distance of 4.26 Å, it demonstrates excellent performance in thin-film transistor devices.
dc.description.sponsorshipWe thank Rutgers University, the British Council (173601536) and the Australian Research Council (DP130101861) for the financial support. This work was performed in part on the SAXS/WAXS beamline at the Australian Synchrotron, Victoria, Australia.
dc.publisherAmerican Chemical Society (ACS)
dc.relation.urlhttp://pubs.acs.org/doi/abs/10.1021/jacs.7b03279
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/jacs.7b03279.
dc.titleAn Alternating 5,5-Dimethylcyclopentadiene-based Copolymer prepared at Room Temperature for High Performance Organic Thin Film Transistors
dc.typeArticle
dc.contributor.departmentKAUST Solar Center (KSC)
dc.contributor.departmentMaterial Science and Engineering Program
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalJournal of the American Chemical Society
dc.eprint.versionPost-print
dc.contributor.institutionDept. Chemistry and Centre for Plastic Electronics, Imperial College London, SW7 2AZ, UK.
dc.contributor.institutionDept. Chemistry, Rutgers University-Newark, Newark, NJ, USA 07102.
dc.contributor.institutionDept. of Materials Science and Engineering, Monash University, Victoria 3800, Australia.
dc.contributor.institutionCSIRO Manufacturing, Victoria 3168, Australia.
kaust.personAnthopoulos, Thomas D.
refterms.dateFOA2018-06-05T00:00:00Z
dc.date.published-online2017-06-12
dc.date.published-print2017-06-21


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