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    Well-Defined Silica Grafted Molybdenum Bis(imido) Catalysts for Imine Metathesis Reactions

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    Type
    Article
    Authors
    Barman, Samir
    Merle, Nicolas cc
    Minenkov, Yury cc
    De Mallmann, Aimery
    Samantaray, Manoja
    Le Quéméner, Frédéric
    Szeto, Kai C.
    Abou-Hamad, Edy cc
    Cavallo, Luigi cc
    Taoufik, Mostafa
    Basset, Jean-Marie cc
    KAUST Department
    Chemical Science Program
    KAUST Catalysis Center (KCC)
    Physical Science and Engineering (PSE) Division
    KAUST Grant Number
    2174 CGR3
    Date
    2017-04-06
    Online Publication Date
    2017-04-06
    Print Publication Date
    2017-04-24
    Permanent link to this record
    http://hdl.handle.net/10754/623934
    
    Metadata
    Show full item record
    Abstract
    Novel site-isolated tetracoordinated molybdenum complexes possessing bis(imido) ligands, [(≡Si–O)2Mo(═NR)2] (R = t-Bu, 2,6-C6H3-i-Pr2), were immobilized on partially dehydroxylated silica (SiO2-200) by a rigorous surface organometallic chemistry protocol. The newly developed materials adorned with bis(imido) functional units, which were previously exploited mainly as spectator ligands on silica-supported olefin metathesis molybdenum catalysts, are found to be efficient heterogeneous catalytic systems for imine cross metathesis under mild conditions.
    Citation
    Barman S, Merle N, Minenkov Y, De Mallmann A, Samantaray MK, et al. (2017) Well-Defined Silica Grafted Molybdenum Bis(imido) Catalysts for Imine Metathesis Reactions. Organometallics 36: 1550–1556. Available: http://dx.doi.org/10.1021/acs.organomet.7b00115.
    Sponsors
    The Competitive Research Grant Program, supported by the KAUST Research Fund (project no. 2174 CGR3) is gratefully acknowledged for financial support. We thank Olivier Mathon for his help during the recording of the XAS spectra on the BM23 beamline at the ESRF (experiment code IN-986).
    Publisher
    American Chemical Society (ACS)
    Journal
    Organometallics
    DOI
    10.1021/acs.organomet.7b00115
    Additional Links
    http://pubs.acs.org/doi/full/10.1021/acs.organomet.7b00115
    ae974a485f413a2113503eed53cd6c53
    10.1021/acs.organomet.7b00115
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

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