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    Nickel-Catalyzed Synthesis of Primary Aryl and Heteroaryl Amines via C–O Bond Cleavage

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    Type
    Article
    Authors
    Yue, Huifeng
    Guo, Lin
    Liu, Xiangqian
    Rueping, Magnus cc
    KAUST Department
    Chemical Science Program
    KAUST Catalysis Center (KCC)
    Physical Science and Engineering (PSE) Division
    Date
    2017-03-13
    Online Publication Date
    2017-03-13
    Print Publication Date
    2017-04-07
    Permanent link to this record
    http://hdl.handle.net/10754/623870
    
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    Abstract
    A nickel-catalyzed protocol for the conversion of aryl and heteroaryl alcohol derivatives to primary and secondary aromatic amines via C(sp2)-O bond cleavage is described. The new amination protocol can be applied to a range of substrates bearing diverse functional groups and uses readily available benzophenone imines as an effective nitrogen source.
    Citation
    Yue H, Guo L, Liu X, Rueping M (2017) Nickel-Catalyzed Synthesis of Primary Aryl and Heteroaryl Amines via C–O Bond Cleavage. Organic Letters 19: 1788–1791. Available: http://dx.doi.org/10.1021/acs.orglett.7b00556.
    Sponsors
    H.Y., L.G., and X.L. were supported by the China Scholarship Council. Financial support by KAUST is gratefully acknowledged.
    Publisher
    American Chemical Society (ACS)
    Journal
    Organic Letters
    DOI
    10.1021/acs.orglett.7b00556
    Additional Links
    http://pubs.acs.org/doi/full/10.1021/acs.orglett.7b00556
    ae974a485f413a2113503eed53cd6c53
    10.1021/acs.orglett.7b00556
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

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