Catalytic Intermolecular Cross-Couplings of Azides and LUMO-Activated Unsaturated Acyl Azoliums
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AbstractAn example for the catalytic synthesis of densely functionalized 1,2,3-triazoles through a LUMO activation mode has been developed. The protocol is enabled by intermolecular cross coupling reactions of azides with in situ-generated alpha,beta-unsaturated acyl azoliums. High yields and broad scope as well as the investigation of reaction mechanism are reported.
CitationLi W, Ajitha MJ, Lang M, Huang K-W, Wang J (2017) Catalytic Intermolecular Cross-Couplings of Azides and LUMO-Activated Unsaturated Acyl Azoliums. ACS Catalysis 7: 2139–2144. Available: http://dx.doi.org/10.1021/acscatal.6b03674.
SponsorsGenerous financial supports are provided by the National Natural Science Foundation of China (21672121, 21502043), the
PublisherAmerican Chemical Society (ACS)