Bane of Hydrogen-Bond Formation on the Photoinduced Charge-Transfer Process in Donor–Acceptor Systems
AuthorsAlsam, Amani A.
Parida, Manas R.
Aly, Shawkat Mohammede
Mohammed, Omar F.
KAUST DepartmentChemical Science Program
Functional Nanomaterials Lab (FuNL)
KAUST Catalysis Center (KCC)
KAUST Solar Center (KSC)
Material Science and Engineering Program
Physical Science and Engineering (PSE) Division
Ultrafast Laser Spectroscopy and Four-dimensional Electron Imaging Research Group
Online Publication Date2017-03-29
Print Publication Date2017-04-13
Permanent link to this recordhttp://hdl.handle.net/10754/623797
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AbstractControlling the ultrafast dynamical process of photoinduced charge transfer at donor acceptor interfaces remains a major challenge for physical chemistry and solar cell communities. The process is complicated by the involvement of other complex dynamical processes, including hydrogen bond formation, energy transfer, and solvation dynamics occurring on similar time scales. In this study, we explore the remarkable impact of hydrogen-bond formation on the interfacial charge transfer between a negatively charged electron donating anionic porphyrin and a positively charged electron accepting pi-conjugated polymer, as a model system in solvents with different polarities and capabilities for hydiogen bonding using femtosecond transient absorption spectroscopy. Unlike the conventional understanding of the key role of hydrogen bonding in promoting the charge-transfer process, our steadystate and time-resolved results reveal that the intervening hydrogen-bonding environment and, consequently, the probable longer spacing between the donor and acceptor molecules significantly hinders the charge-transfer process between them. These results show that site-specific hydrogen bonding and geometric considerations between donor and acceptor can be exploited to control both the charge-transfer dynamics and its efficiency not only at donor acceptor interfaces but also in complex biological systems.
CitationAlsam AA, Adhikari A, Parida MR, Aly SM, Bakr OM, et al. (2017) Bane of Hydrogen-Bond Formation on the Photoinduced Charge-Transfer Process in Donor–Acceptor Systems. The Journal of Physical Chemistry C 121: 7837–7843. Available: http://dx.doi.org/10.1021/acs.jpcc.7b00072.
SponsorsThis work was supported by King Abdullah University of Science and Technology (KAUST). Part of this work was supported by Saudi Basic Industries Corporation (SABIC) grant RGC/3/2470-01.
PublisherAmerican Chemical Society (ACS)