Show simple item record

dc.contributor.authorSantoro, Orlando
dc.contributor.authorNahra, Fady
dc.contributor.authorCordes, David B.
dc.contributor.authorSlawin, Alexandra M.Z.
dc.contributor.authorNolan, Steven P.
dc.contributor.authorCazin, Catherine S. J.
dc.date.accessioned2017-05-15T10:35:10Z
dc.date.available2017-05-15T10:35:10Z
dc.date.issued2016-06-04
dc.identifier.citationSantoro O, Nahra F, Cordes DB, Slawin AMZ, Nolan SP, et al. (2016) Synthesis, characterization and catalytic activity of stable [(NHC)H][ZnXY 2 ] (NHC = N -Heterocyclic carbene, X, Y = Cl, Br) species. Journal of Molecular Catalysis A: Chemical 423: 85–91. Available: http://dx.doi.org/10.1016/j.molcata.2016.05.031.
dc.identifier.issn1381-1169
dc.identifier.doi10.1016/j.molcata.2016.05.031
dc.identifier.urihttp://hdl.handle.net/10754/623602
dc.description.abstractThe synthesis and characterization of imidazol(in)ium-based zinc(II) halide salts are reported. These compounds present interesting structural features and exhibit high stability. Their catalytic activity was explored in the methylation of amines with CO2 and PhSiH3.
dc.description.sponsorshipThe authors gratefully acknowledge the Royal Society (University Research Fellowship to C.S.J.C) and the EPSRC (EP/J500549/1, EP/K00445X/1) for funding. S.P.N. acknowledges support from KSU.This publication is based upon some work supported by the King Abdullah University of Science and Technology (KAUST) Office of Sponsored Research (OSR) under Award No. OSR-2015-CCF-1974-03.
dc.publisherElsevier BV
dc.subjectN-Heterocyclic carbenes
dc.subjectZinc
dc.subjectMethylation
dc.subjectCO2
dc.titleSynthesis, characterization and catalytic activity of stable [(NHC)H][ZnXY2] (NHC=N-Heterocyclic carbene, X, Y=Cl, Br) species
dc.typeArticle
dc.identifier.journalJournal of Molecular Catalysis A: Chemical
dc.contributor.institutionEaStCHEM School of Chemistry, University of St. Andrews, St Andrews KY16 9ST, UK
dc.contributor.institutionUniversiteit Gent, Department of Inorganic and Physical Chemistry, Krijgslaan 281, S-3, B-9000 Ghent, Belgium
dc.contributor.institutionKing Saud University, Department of Chemistry, College of Sciences, P.O. Box 2455, Riyadh 11451, Saudi Arabia
kaust.grant.numberOSR-2015-CCF-1974-03


This item appears in the following Collection(s)

Show simple item record