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    Gold- N -Heterocyclic Carbene Complexes of Mineral Acids

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    Type
    Article
    Authors
    Brill, Marcel
    Nahra, Fady cc
    Gómez-Herrera, Alberto
    Zinser, Caroline
    Cordes, David B. cc
    Slawin, Alexandra M. Z.
    Nolan, Steven P. cc
    KAUST Grant Number
    OSR-2015-CCF-1974-03
    Date
    2016-12-14
    Online Publication Date
    2016-12-14
    Print Publication Date
    2017-01-09
    Permanent link to this record
    http://hdl.handle.net/10754/623551
    
    Metadata
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    Abstract
    We have synthesized and characterized new gold-N-heterocyclic carbene (NHC) complexes derived from the deprotonation of mineral acids. The use of sulfuric acid was a particularly interesting case. These complexes were tested in known gold-catalyzed reactions, such as the hydration of alkynes and the Meyer–Schuster rearrangement. They proved to be highly efficient in both reactions.
    Citation
    Brill M, Nahra F, Gómez-Herrera A, Zinser C, Cordes DB, et al. (2016) Gold- N -Heterocyclic Carbene Complexes of Mineral Acids. ChemCatChem 9: 117–120. Available: http://dx.doi.org/10.1002/cctc.201601290.
    Sponsors
    The authors gratefully acknowledge King Saud University for funding. This publication is based upon work partly supported by the King Abdullah University of Science and Technology (KAUST) Office of Sponsored Research (OSR) under Award No. OSR-2015-CCF-1974-03.
    Publisher
    Wiley
    Journal
    ChemCatChem
    DOI
    10.1002/cctc.201601290
    ae974a485f413a2113503eed53cd6c53
    10.1002/cctc.201601290
    Scopus Count
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