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dc.contributor.advisorHuang, Kuo-Wei
dc.contributor.authorAng, Eleanor Pei Ling
dc.date.accessioned2017-05-11T09:19:15Z
dc.date.available2017-05-11T09:19:15Z
dc.date.issued2017-04
dc.identifier.citationAng, E. P. L. (2017). Transfer Hydrogenation: Employing a Simple, In Situ Prepared Catalytic System. KAUST Research Repository. https://doi.org/10.25781/KAUST-56JC3
dc.identifier.doi10.25781/KAUST-56JC3
dc.identifier.urihttp://hdl.handle.net/10754/623471
dc.description.abstractTransfer hydrogenation has been recognized to be an important synthetic method in both academic and industrial research to obtain valuable products including alcohols. Transition metal catalysts based on precious metals, such as Ru, Rh and Ir, are typically employed for this process. In recent years, iron-based catalysts have attracted considerable attention as a greener and more sustainable alternative since iron is earth abundant, inexpensive and non-toxic. In this work, a combination of iron disulfide with chelating bipyridine ligand was found to be effective for the transfer hydrogenation of a variety of ketones to the corresponding alcohols in the presence of a simple base. It provided a convenient and economical way to conduct transfer hydrogenation. A plausible role of sulfide next to the metal center in facilitating the catalytic reaction is demonstrated.
dc.language.isoen
dc.subjectTransfer hydrogenation
dc.subjectReduction
dc.subjectKetones
dc.subjectIron-catalyzed
dc.subjectIn situ
dc.titleTransfer Hydrogenation: Employing a Simple, In Situ Prepared Catalytic System
dc.typeThesis
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
thesis.degree.grantorKing Abdullah University of Science and Technology
dc.contributor.committeememberEppinger, Jörg
dc.contributor.committeememberLai, Zhiping
thesis.degree.disciplineChemical Science
thesis.degree.nameMaster of Science
refterms.dateFOA2018-06-13T16:21:33Z


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