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    Synthesis and Characterization of Hexahapto-Chromium Complexes of Single-Walled Carbon Nanotubes

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    Type
    Book Chapter
    Authors
    Kalinina, Irina
    Bekyarova, Elena
    Sarkar, Santanu
    Itkis, Mikhail E.
    Niyogi, Sandip
    Jha, Neetu
    Wang, Qingxiao
    Zhang, Xixiang cc
    Al-Hadeethi, Yas Fadel
    Haddon, Robert C.
    KAUST Department
    Electron Microscopy
    Imaging and Characterization Core Lab
    Material Science and Engineering Program
    Nanofabrication Core Lab
    Physical Science and Engineering (PSE) Division
    Date
    2016-12-16
    Permanent link to this record
    http://hdl.handle.net/10754/623429
    
    Metadata
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    Abstract
    This chapter employs purified pristine single-walled carbon nanotubes (SWNTs) and octadecylaminefunctionalized-SWNTs. These SWNTs are employed for investigate the potential of the SWNT sidewall to function as a hexahapto ligand for chromium (Cr), with in-depth characterization of the products using some of the techniques, such as thermogravimetric analysis (TGA), transmission electron microscopy (TEM), x-ray photoelectron spectroscopy (XPS). Purified electric arc (EA)-produced SWNTs (P2-SWNT) and octadecylaminefunctionalized SWNTs were obtained from Carbon Solutions, Inc. The TEM images show the removal of the Cr particles from the outer surface of the SWNT bundles in the SWNT-Cr complexes after decomplexation; Cr attachment to the surface of the as-prepared complexes (η6-SWNT)Cr(CO)3 and (η6-SWNT-CONH(CH2)17CH3)Cr(CO)3 is clearly evident. The positions of the bands in the Raman spectra of SWNTs are sensitive to doping and thus the chapter examines the effect of complexation of the Cr(CO)3 and Cr(η6-benzene) units on the position of the G and 2D bands in the (η6-SWNT)Cr(CO)3 and (η6-SWNT)Cr(η6-benzene) complexes.
    Citation
    Kalinina I, Bekyarova E, Sarkar S, Itkis ME, Niyogi S, et al. (2016) Synthesis and Characterization of Hexahapto-Chromium Complexes of Single-Walled Carbon Nanotubes. Chemical Synthesis and Applications of Graphene and Carbon Materials: 87–114. Available: http://dx.doi.org/10.1002/9783527648160.ch6.
    Publisher
    Wiley
    Journal
    Chemical Synthesis and Applications of Graphene and Carbon Materials
    DOI
    10.1002/9783527648160.ch6
    Additional Links
    http://onlinelibrary.wiley.com/doi/10.1002/9783527648160.ch6/summary
    ae974a485f413a2113503eed53cd6c53
    10.1002/9783527648160.ch6
    Scopus Count
    Collections
    Nanofabrication Core Lab; Imaging and Characterization Core Lab; Physical Science and Engineering (PSE) Division; Material Science and Engineering Program; Book Chapters

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