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dc.contributor.authorVillalobos, Luis Francisco
dc.contributor.authorHuang, Tiefan
dc.contributor.authorPeinemann, Klaus-Viktor
dc.date.accessioned2017-05-02T13:22:29Z
dc.date.available2017-05-02T13:22:29Z
dc.date.issued2017-04-24
dc.identifier.citationVillalobos LF, Huang T, Peinemann K-V (2017) Cyclodextrin Films with Fast Solvent Transport and Shape-Selective Permeability. Advanced Materials: 1606641. Available: http://dx.doi.org/10.1002/adma.201606641.
dc.identifier.issn0935-9648
dc.identifier.doi10.1002/adma.201606641
dc.identifier.urihttp://hdl.handle.net/10754/623312
dc.description.abstractThis study describes the molecular-level design of a new type of filtration membrane made of crosslinked cyclodextrins-inexpensive macrocycles of glucose, shaped like hollow truncated cones. The channel-like cavities of cyclodextrins spawn numerous paths of defined aperture in the separation layer that can effectively discriminate between molecules. The transport of molecules through these membranes is highly shape-sensitive. In addition, the presence of hydrophobic (cavity) and hydrophilic (ester-crosslinked outer part) domains in these films results in high permeances for both polar and nonpolar solvents.
dc.description.sponsorshipThis research was supported by King Abdullah University of Science and Technology (KAUST). The authors are grateful to Kexin Yao for assisting with the CO2 adsorption experiments and to Mohamed Nejib Hedhili for performing the XPS analysis. The authors thank Rachid Sougrat, Stefan Chisca, Mahendra Kumar, Rahul Shevate, and Federico Pacheco for discussions.
dc.publisherWiley-Blackwell
dc.relation.urlhttp://onlinelibrary.wiley.com/doi/10.1002/adma.201606641/full
dc.rightsThis is the peer reviewed version of the following article: Cyclodextrin Films with Fast Solvent Transport and Shape-Selective Permeability, which has been published in final form at http://doi.org/10.1002/adma.201606641. This article may be used for non-commercial purposes in accordance With Wiley Terms and Conditions for self-archiving.
dc.subjectCyclodextrins
dc.subjectMembranes
dc.subjectNanofiltration
dc.subjectInterfacial Polymerization
dc.titleCyclodextrin Films with Fast Solvent Transport and Shape-Selective Permeability
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.identifier.journalAdvanced Materials
dc.eprint.versionPost-print
kaust.personVillalobos, Luis Francisco
kaust.personHuang, Tiefan
kaust.personPeinemann, Klaus-Viktor
refterms.dateFOA2018-04-24T00:00:00Z


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