Molecule-Level g-C3N4 Coordinated Transition Metals as a New Class of Electrocatalysts for Oxygen Electrode Reactions
Li, Lu Hua
KAUST DepartmentAdvanced Membranes and Porous Materials Research Center
Chemical Science Program
Nanostructured Functional Materials (NFM) laboratory
Physical Science and Engineering (PSE) Division
Online Publication Date2017-02-27
Print Publication Date2017-03-08
Permanent link to this recordhttp://hdl.handle.net/10754/623192
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AbstractOrganometallic complexes with metal-nitrogen/carbon (M-N/C) coordination are the most important alternatives to precious metal catalysts for oxygen reduction and evolution reactions (ORR and OER) in energy conversion devices. Here, we designed and developed a range of molecule-level graphitic carbon nitride (g-C3N4) coordinated transition metals (M-C3N4) as a new generation of M-N/C catalysts for these oxygen electrode reactions. As a proof-of-concept example, we conducted theoretical evaluation and experimental validation on a cobalt-C3N4 catalyst with a desired molecular configuration, which possesses comparable electrocatalytic activity to that of precious metal benchmarks for the ORR and OER in alkaline media. The correlation of experimental and computational results confirms that this high activity originates from the precise M-N2 coordination in the g-C3N4 matrix. Moreover, the reversible ORR/OER activity trend for a wide variety of M-C3N4 complexes has been constructed to provide guidance for the molecular design of this promising class of catalysts.
CitationZheng Y, Jiao Y, Zhu Y, Cai Q, Vasileff A, et al. (2017) Molecule-Level g-C3N4 Coordinated Transition Metals as a New Class of Electrocatalysts for Oxygen Electrode Reactions. Journal of the American Chemical Society 139: 3336–3339. Available: http://dx.doi.org/10.1021/jacs.6b13100.
SponsorsWe acknowledge financial support by the Australian Research Council (DP 170104464, DP160104866, DP140104062, and DE160101163). NEXAFS and EXAFS were performed at Australian Synchrotron. DFT calculations were carried out using the NCI National Facility systems.
PublisherAmerican Chemical Society (ACS)