Decarbonylative Silylation of Esters by Combined Nickel and Copper Catalysis for the Synthesis of Arylsilanes and Heteroarylsilanes
KAUST DepartmentKAUST Catalysis Center (KCC)
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AbstractAn efficient nickel/copper-catalyzed decarbonylative silylation reaction of carboxylic acid esters with silylboranes is described. This reaction provides access to structurally diverse silanes with high efficiency and excellent functional-group tolerance starting from readily available esters.
CitationGuo L, Chatupheeraphat A, Rueping M (2016) Decarbonylative Silylation of Esters by Combined Nickel and Copper Catalysis for the Synthesis of Arylsilanes and Heteroarylsilanes. Angewandte Chemie International Edition 55: 11810–11813. Available: http://dx.doi.org/10.1002/anie.201604696.
SponsorsL. Guo was supported by the China Scholarship Council.