Decarbonylative Silylation of Esters by Combined Nickel and Copper Catalysis for the Synthesis of Arylsilanes and Heteroarylsilanes
KAUST DepartmentChemical Science Program
KAUST Catalysis Center (KCC)
Physical Sciences and Engineering (PSE) Division
Online Publication Date2016-08-25
Print Publication Date2016-09-19
Permanent link to this recordhttp://hdl.handle.net/10754/623150
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AbstractAn efficient nickel/copper-catalyzed decarbonylative silylation reaction of carboxylic acid esters with silylboranes is described. This reaction provides access to structurally diverse silanes with high efficiency and excellent functional-group tolerance starting from readily available esters.
CitationGuo L, Chatupheeraphat A, Rueping M (2016) Decarbonylative Silylation of Esters by Combined Nickel and Copper Catalysis for the Synthesis of Arylsilanes and Heteroarylsilanes. Angewandte Chemie International Edition 55: 11810–11813. Available: http://dx.doi.org/10.1002/anie.201604696.
SponsorsL. Guo was supported by the China Scholarship Council.